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Inverse identification framework for cohesive zone model incorporating failure mode based on multi-island genetic algorithm

Composite interfaces are commonly simulated by cohesive zone models with the key challenge being the calibration of interfacial parameters. A new framework is presented in this paper to derive the characteristic of any cohesive zone model. This approach employs the multi-island genetic algorithm to obtain the interface parameters aligning closely with the experimental observations. The introduced framework innovatively formulates an objective function, considering both the congruence of the load-displacement curve and the alignment with the failure mode of model. The framework combines machine learning and multi-objective optimization. A method using the interface debonding length to quantify the failure mode of the model is proposed. To demonstrate the feasibility of the proposed framework, the newly strength-based cohesive zone model is taken as an example, and key parameters and damage evolution are identified accurately. The inverse algorithm is used to identify the interface parameters of both the double cantilever beam experiment and the four-point bending test. The robustness and accuracy of the framework are validated through the double cantilever beam test. The findings indicate that the numerical results align closely with the experimental data, confirming that the interface parameters identified by the proposed framework can reproduce the performance of the adhesive joints.

physics.app-ph↗

Supercritical Water Gasification: Practical Design Strategies and Operational Challenges for Lab-Scale, Continuous Flow Reactors

Optimizing an industrial-scale supercritical water gasification process requires detailed knowledge of chemical reaction pathways, rates, and product yields. Laboratory-scale reactors are employed to develop this knowledge base. The rationale behind designs and component selection of continuous flow, laboratory-scale supercritical water gasification reactors is analyzed. Some design challenges have standard solutions, such as pressurization and preheating, but issues with solid precipitation and feedstock pretreatment still present open questions. Strategies for reactant mixing must be evaluated on a system-by-system basis, depending on feedstock and experimental goals, as mixing can affect product yields, char formation, and reaction pathways. In-situ Raman spectroscopic monitoring of reaction chemistry promises to further fundamental knowledge of gasification and decrease experimentation time. High-temperature, high-pressure spectroscopy in supercritical water conditions is performed, however, long-term operation flow cell operation is challenging. Comparison of Raman spectra for decomposition of formic acid in the supercritical region and cold section of the reactor demonstrates the difficulty in performing quantitative spectroscopy in the hot zone. Future designs and optimization of SCWG reactors should consider well-established solutions for pressurization, heating, and process monitoring, and effective strategies for mixing and solids handling for long-term reactor operation and data collection.

physics.app-ph↗

Model for Nitric oxide and its dayglow emission in the Martian upper atmosphere using NGIMS/MAVEN measured neutral and ion densities

A comprehensive study of Nitric oxide (NO) chemistry in the Martian upper atmosphere is restricted due to the lack of requisite measurements. NO is an abundant form of odd nitrogen species in the Martian lower atmosphere and its density depends on several photochemical processes. We have developed a photochemical model to study the NO density in the dayside of Martian upper atmosphere by accounting for various production and loss mechanisms. By utilizing the Neutral Gas and Ion Mass Spectrometer (NGIMS) on-board Mars Atmosphere and Volatile Evolution (MAVEN) mission measured neutral and ion densities during deep dip 8 and 9 campaigns, we modelled NO number density in the Martian sunlit upper atmosphere for the altitudes between 120 and 200 km. The modelled NO densities are employed to calculate NO (1,0) gamma band emission intensity profiles in the dayside upper atmosphere of Mars. The calculated NO density and its gamma band intensity profiles are found to be consistent with Imaging Ultraviolet Spectrograph (IUVS) onboard MAVEN observations and also with other modelling studies. We found that the local CO2 and N2 density variations can lead to a change in NO density and consequently its dayglow intensity by a factor of 2 to 5. Since NO is a trace constituent and also its dayglow emissions are strongly obscured by CO Cameron band emissions, we suggest that the derivation of NO number density based on our approach can constrain its abundance in the dayside upper atmosphere of Mars. More observations of (1-0) gamma band emission along with modelling will help to study the global distribution of NO in the Martian atmosphere.

astro-ph.EP↗

Synthesis and characterization of cotton fiber-based nanocellulose

Nanocellulose prepared from the natural material has a promising wide range of opportunities to obtain the superior material properties towards various end-products. In this research, commercially available natural cotton was treated with aqueous sodium hydroxide solution to eliminate the hemicellulose and lignin, then cellulose was collected. The collected cellulose was subjected to acid hydrolysis using sulphuric acid to obtain nanocellulose. The prepared nanocellulose was further characterized with the aid of Fourier transform infrared spectroscopy, X-ray diffraction and Scanning Electron Microscopy to elucidate the chemical structure, crystallinity and the morphology.

physics.app-ph↗

A new experimental method to study the influence of welding residual stresses on fatigue crack propagation

This paper presents a study on the influence of welding residual stresses (RS) on fatigue crack propagation rate (FCPR) in mode I. The objective of this work is to develop a novel methodology that allows a variation of a RS field in the studied specimen while keeping constant all other variables influencing FCPR. This led to the development of a novel specimen geometry, named CT-RES, in which RS are introduced by weld bead deposition far from the region in which fatigue crack propagation (FCP) occurs. As a consequence, the effect of factors influencing FCPR other than RS such as microstructural changes or plastic deformation, often introduced by welding processes, can be avoided. The welding RS introduced in the CT-RES specimen were determined by the contour method and the weight functions method was used to calculate the stress intensity factor (SIF), Kres, resulting from the RS as the fatigue crack propagates into the specimen. The evolution of cyclic stress ratio at the crack tip, Rlocal, was then computed from Kres to quantify the influence of RS on the cyclic stress ratio. The results show that for a given stress intensity range, dK, the FCPR of the welded geometry with fixed externally low R ratio (R = 0.1), but constantly increasing Rlocal, is the same as for the as-machined geometry without RS, solicited at high cyclic stress ratio (R = 0.7). These observations partially validate the BS7910 standard philosophy in which the remaining life of a flawed structure in presence of tensile RS is calculated from a high cyclic stress ratio (R > 0.5) crack propagation curve to eliminate crack closure effects.

physics.app-ph↗

Unsteady aerodynamic effects in small-amplitude pitch oscillations of an airfoil

High-fidelity wall-resolved large-eddy simulations (LES) are utilized to investigate the flow-physics of small-amplitude pitch oscillations of an airfoil at Re = 100,000. The investigation of the unsteady phenomenon is done in the context of natural laminar flow airfoils, which can display sensitive dependence of the aerodynamic forces on the angle of attack in certain "off-design" conditions. The dynamic range of the pitch oscillations is chosen to be in this sensitive region. Large variations of the transition point on the suction-side of the airfoil are observed throughout the pitch cycle resulting in a dynamically rich flow response. Changes in the stability characteristics of a leading-edge laminar separation bubble has a dominating influence on the boundary layer dynamics and causes an abrupt change in the transition location over the airfoil. The LES procedure is based on a relaxation-term which models the dissipation of the smallest unresolved scales. The validation of the procedure is provided for channel flows and for a stationary wing at Re = 400,000.

physics.flu-dyn↗

A First Look at the Performance of Nano-Grooved Heat Pipes

Passive thermal spreaders utilizing liquid/vapor phase-change mechanism such as heat pipes, have been widely used in the macro-scale thermal management of electronic devices for many years. Micro-fabrication techniques enabled the fabrication micro-scale grooved heat pipes on semiconductors. Recent advances in fabrication techniques, on the other hand, enabled producing nano- and Ångström-scale capillaries and cavities, which renders the manufacturing of nanoscale heat pipes possible. In the present study, we have simulated nanoscale heat pipes composed of nano-grooves using molecular dynamics and evaluated their performance based on different operating parameters such as the filling ratio and heat load. Moreover, evaluation of size effect on the thermal performance is made by comparing proportionally scaled heat pipes. Simulation results reveal that efficient operation of nano-grooved heat pipes depend not only on the proper selections of filling ratio and heat load, but also on the geometrical parameters such as cross sectional dimensions and aspect ratio of the groove. The modeling strategy used in this study opens an opportunity for computational experimentation of nanoscale heat pipes.

physics.app-ph↗

Nanosecond laser ablation of Si(111) under an aqueous medium

Nanosecond laser ablation of p-type Si(111) wafer is presented under an ambient, a water and a glycerin conditions. Effects of pulse energy, number of pulses and type of environment are systematically analyzed with an Optical Profilometer, a Scanning Electron Microscope and an Atomic Force Microscope. Obtained results are compared with Zemax-EE simulations. Self-assembly nano-ripple formation has been observed in an ambient condition. However, these ripples and heat affected zone (HAZ) area disappeared in aqueous medium which enhances the quality of ablation. Moreover, no remarkable oxidation was obtained in ablation zone even in an ambient condition based on the SEM-EDX analysis. Ablation profiles and their depths for different environments are compared with false color technique. Although ablation diameters are comparable each other, their depths are small enough in aqueous medium to control depth profile of damaged area. According to our results, best ablation profiles (precise edges without HAZ) are achieved under an aqueous medium especially in glycerin conditions both in low and high pulse energy regime.

physics.app-ph↗

Interfacial thermal resistance between porous layers: impact on thermal conductivity of a multilayered porous structure

Features of thermal transport in multilayered porous silicon nanostructures are considered. Such nanostructures were fabricated by electrochemical etching of monocrystalline Si substrates by applying periodically changed current density. Hereby, the multilayered structures with specific phononic properties were formed. Photoacoustic (PA) technique in gas-microphone configuration was applied for thermal conductivity evaluation. Experimental amplitude-frequency dependencies were adjusted by temperature distribution simulation with thermal conductivity of the multilayered porous structure as a fitting parameter. The experimentally determined values of thermal conductivity were found to be significantly lower than theoretically calculated ones. Such difference was associated with the presence of thermal resistance at the interfaces between porous layers with different porosities arising because of elastic parameters mismatch (acoustical mismatch). Accordingly, the magnitude of this interfacial thermal resistance was experimentally evaluated for the first time. Furthermore, crucial impact of the resistance on thermal transport perturbation in a multilayered porous silicon structure was revealed.

physics.app-ph↗

The effect of disjoining pressure on the shape of condensing films in a fin-groove corner

Thin film condensation is commonly present in numerous natural and artificial processes. Phase-change driven passive heat spreaders such as heat pipes, which are widely used in electronics cooling, employ a continuous condensation process at the condenser region. When the wick structure of a heat pipe is composed of grooves, the top surfaces of the walls (fins) located between consecutive grooves function as the major source of condensation and the condensate flows along the fin top into the grooves. Modeling of this condensation problem is vital for the proper estimation of condensation heat transfer, which constitutes the basis for the overall performance of an heat pipe together with the evaporation process. In the current study, a solution methodology is developed to model the condensation and associated liquid flow in a fin-groove system. Conservation of mass and momentum equations, augmented Young-Laplace equation and Kucherov-Rikenglaz equation are solved simultaneously to calculate the film thickness profile. The model proposed enables the investigation of the effect of disjoining pressure on the film profile by keeping the fin-groove corner, where the film becomes thinnest, inside the solution domain. The results show that dispersion forces become effective for near isothermal systems with sharp fin-groove corners and the film profile experiences an abrupt change, a slope break, in the close proximity of the corner. The current study is the first computational confirmation of this behavior in the literature.

physics.app-ph↗

Reversible and irreversible changes in physical and mechanical properties of biocomposites during hydrothermal aging

The use of biocomposites on a daily basis for industrial products brings to light the influence of environmental factors on the evolution of mechanical properties. This aging has a major influence in the lifetime of any product based on such materials. Among biobased composites, poly(lactic acid) reinforced with plant fibers are known to be sensitive to hydrothermal aging due to the intrinsic nature of their components. Although some papers studied the influence of temperature and water absorption on such materials, so far the difference between reversible and irreversible effects of aging has been hardly studied. This distinction is the purpose of this study. Poly(lactic acid) samples reinforced with various content of flax fibers (0%, 10%, and 30%) were immersed in water at different temperature (20, 35, and 50{\textdegree}C) up to 51 days. The physical and chemical phenomena responsible for the changes in the mechanical properties of biocomposites were evaluated. It was observed that these changes were mainly reversible. However, irreversible effects of aging turned out to increase drastically with the amount of fiber and the aging temperature. While hydrolysis drastically deteriorated PLA for longer aging times, the lifetime of biocomposites was significantly extended (+ 230% at 50{\textdegree}C from 0% to 10% in fiber content) by the presence of fibers which postponed the failure of PLA.

physics.app-ph↗

Examining an Image Reconstruction Method in Infrared Emission Tomography

We present and evaluate the application of the "Reconstructed Image from Simulations Ensemble" (RISE), a novel tomographic image reconstruction method, in infrared tomography. We demonstrate that established methods of photon emission tomography, widely used with penetrating ionizing radiation, are applicable to infrared radiation. RISE, the method of choice, employs statistical physics concepts and utilizes Monte Carlo techniques to construct the imaged object from its infrared planar projections. The validity of the InfraRed Emission Tomographic (IRET) method is demonstrated, and the efficacy of RISE is evaluated with A) simulated data and B) experimental sets of infrared projections obtained from a thermal phantom with an infrared camera. For the simulation studies presented, the reconstructed images obtained with RISE and the well - known Algebraic Reconstruction Technique (ART) and Maximum Likelihood Expectation Maximization (MLEM) method were evaluated using well-established metrics.

physics.med-ph↗

Demonstration of Si based InAs/GaSb type-II superlattice p-i-n photodetector

In this paper, mid-wave infrared photodetection based on an InAs/GaSb type-II superlattice p-i-n photodetector grown directly on Si substrate is demonstrated and characterized. Excitation power dependence on integrated intensity from the photoluminescence measurements reveals a power coefficient of P~I0.74, indicating that defects related process is playing an important role in the predominant recombination channel for photogenerated carriers. At 70 K, the device exhibits a dark current density of 2.3 A/cm2 under -0.1 V bias. Arrhenius analysis of dark current shows activation energies much less than half of the active layer bandgap, which suggests that the device is mainly limited by surface leakage and defect-assisted tunneling, consistent with the photoluminescence analysis. The detector shows 50% cutoff wavelength at ~5.5 um at 70 K under bias of -0.1 V. The corresponding peak responsivity and specific detectivity are 1.2 A/W and 1.3*10e9 cm*Hz1/2/W, respectively. Based on these optoelectronics characterization results, reduction of defects by optimizing the III/V-Si interface, and suppression of surface leakage channels are argued to be the main factors for performance improvement in this Si-based T2SL detector towards low cost, large-format MWIR detection system on Si photonics platform.

physics.app-ph↗

Room-Temperature Processing of Inorganic Perovskite Films to Enable Flexible Solar Cells

Inorganic lead halide perovskite materials have attracted great attention recently due to their potential for greater thermal stability compared to hybrid organic perovskites. However, the high processing temperature to convert from the non-perovskite phase to cubic perovskite phase in many of these systems has limited their application in flexible optoelectronic devices. Here, we report a room temperature processed inorganic PSC based on CsPbI2Br as the light harvesting layer. By combing this composition with key precursor solvents, we show that the inorganic perovskite film can be prepared by the vacuum-assist method under room temperature conditions in air. Unencapsulated devices achieved the power conversion efficiency up to 8.67% when measured under 1-sun irradiation. Exploiting this room temperature process, flexible inorganic PSCs based on an inorganic metal halide perovskite material is demonstrated.

physics.app-ph↗

Effects of pyrolysis temperature on the hydrologically relevant porosity of willow biochar

Biochar pore space consists of porosity of multiple length scales. In direct water holding applications like water storage for plant water uptake, the main interest is in micrometre-range porosity since these pores are able to store water that is easily available for plants. Gas adsorption measurements which are commonly used to characterize the physical pore structure of biochars are not able to quantify this pore-size range. While pyrogenetic porosity (i.e. pores formed during pyrolysis process) tends to increase with elevated process temperature, it is uncertain whether this change affects the pore space capable to store plant available water. In this study, we characterized biochar porosity with x-ray tomography which provides quantitative information on the micrometer-range porosity. We imaged willow dried at 60 $^\circ$C and biochar samples pyrolysed in three different temperatures (peak temperatures 308, 384, 489 $^\circ$C, heating rate 2 $^\circ$C min$^{-1}$). Samples were carefully prepared and traced through the experiments, which allowed investigation of porosity development in micrometre size range. Pore space was quantified with image analysis of x-ray tomography images and, in addition, nanoscale porosity was examined with helium ion microscopy. The image analysis results show that initial pore structure of the raw material determines the properties of micrometre-range porosity in the studied temperature range. Thus, considering the pore-size regime relevant to the storage of plant available water, pyrolysis temperature in the studied range does not provide means to optimize the biochar structure. However, these findings do not rule out that process temperature may affect the water retention properties of biochars by modifying the chemical properties of the pore surfaces.

cond-mat.mtrl-sci↗

Effect of Gd and Co content on electrochemical and electronic properties of La$_{1.5}$Mg$_{0.5}$Ni$_7$ alloys: a combined experimental and first-principles study

In this work, we investigate the effect of Gd and Co substitutions on the electrochemical and electronic properties of La$_{1.5}$Mg$_{0.5}$Ni$_7$ alloy. Two series of La$_{1.5-x}$Gd$_x$Mg$_{0.5}$Ni$_7$ ($x$ = 0.0, 0.25, 1.0) and La$_{1.5}$Mg$_{0.5}$Ni$_{7-y}$Co$_y$ ($y$ = 0.0, 0.5, 1.5) alloys are produced using mechanical alloying technique. The X-ray diffraction indicates multiphase character of the samples, with the majority of hexagonal Ce$_2$Ni$_7$-type and rhombohedral Gd$_2$Co$_7$-type structures of (La,Mg)$_2$Ni$_7$ phase. Partial substitutions of La by Gd or Ni by Co in La$_{1.5}$Mg$_{0.5}$Ni$_7$ phase result in increase of cycle stability of the metal hydride (MH$_x$) electrodes. All considered alloys reach the maximum discharge capacity after three charging-discharging cycles. Two optimal compositions, in respect of electrochemical properties, are subsequently investigated by the X-ray photoelectron spectroscopy (XPS). The experimental analysis of the valence band is further extended by the density functional theory (DFT) calculations. We also discuss the effects of alloying and site preference of dopants on the position of the van Hove-type singularity, as observed in the electronic densities of states (DOS) in proximity of the Fermi level.

cond-mat.mtrl-sci↗

Electrical characteristics of vertical-geometry Schottky junction to magnetic insulator (Ga,Mn)N heteroepitaxially grown on sapphire

Schottky barrier height and the ideality factor $η$ are established for the first time in the single phase (Ga,Mn)N using a vertical geometry device. The material has been heteroepitaxially grown on commercially available low threading dislocation density GaN:Si template. The observed above 10M$Ω$ resistances already at room temperature are indicative that a nearly conductive-dislocation-free electrical properties are achieved. The analysis of temperature dependence of the forward bias I-V characteristics in the frame of the thermionic emission model yields Ti-(Ga,Mn)N Schottky barrier height to be slightly lower but close in character to other metal/GaN junctions. However, the large magnitudes of the ideality factor $η$>1.5 for T$\leqslant$300K, point to a sizable current blocking in the structure. While it remains to be seen whether it is due to the presence of (Ga,Mn)N barrier or due to other factors which reduce the effective area of the junction, an existence of a substantial serial resistance may hold the key to explain similar observations in other devices of a corresponding structure and technological relevance.

physics.app-ph↗

Zirconia nano-colloids transfer from continuous hydrothermal synthesis to inkjet printing

Water dispersion of nanometric yttria stabilized zirconia (YSZ) particles synthesized by continuous hydrothermal synthesis are transferred into nanoinks for thin film deposition. YSZ nanoparticles are synthesized in supercritical conditions resulting in highly dispersed crystals of 10 nm in size. The rheology of the colloid is tailored to achieve inkjet printability (Z) by using additives for regulating viscosity and surface tension. Inks with a wide range of properties are produced. A remarkable effect of nanoparticles on the ink printability is registered even at solid load < 1% vol. In particular, nanoparticles hinder the droplet formation at low values of the printability while suitable jetting is observed at high Z values, i.e. Z ca. 20. For the optimized inks, we achieve high quality printing with lateral and thickness resolution of 70 um and ca. 250 nm respectively, as well as self levelling effect with a reduction of the substrate roughness. Densification is achieved at sintering temperatures below 1200 C.

physics.app-ph↗