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arXiv · 0705.3660

Fluctuation-dissipation ratios in the dynamics of self-assembly

Robert L. Jack·Michael F. Hagan·David Chandler
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Abstract

We consider two seemingly very different self-assembly processes: formation of viral capsids, and crystallization of sticky discs. At low temperatures, assembly is ineffective, since there are many metastable disordered states, which are a source of kinetic frustration. We use fluctuation-dissipation ratios to extract information about the degree of this frustration. We show that our analysis is a useful indicator of the long term fate of the system, based on the early stages of assembly.

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BibTeXRIS

Robert L. Jack, Michael F. Hagan, David Chandler. 2007-08-10. Fluctuation-dissipation ratios in the dynamics of self-assembly. https://doi.org/10.1103/physreve.76.021119

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