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arXiv · 0808.2855

Comment on "Failure of the work-Hamiltonian connection for free-energy calculations" by Jose M. G. Vilar and J. Miguel Rubi

Luca Peliti
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Abstract

I point out that the arguments raised by Vilar and Rubi against the work-Hamiltonian connection in free-energy calculations imply, if correct, the failure of the statistical mechanical expression of the thermodynamical free-energy via the logarithm of the partition function.

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Luca Peliti. 2008-08-21. Comment on "Failure of the work-Hamiltonian connection for free-energy calculations" by Jose M. G. Vilar and J. Miguel Rubi. https://doi.org/10.1103/physrevlett.101.098903

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