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arXiv · 0911.2070

Derivation of Boltzmann Principle

Michele Campisi·Donald H. Kobe
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Abstract

We present a derivation of Boltzmann principle $S_{B}=k_{B}\ln \mathcal{W}$ based on classical mechanical models of thermodynamics. The argument is based on the heat theorem and can be traced back to the second half of the nineteenth century with the works of Helmholtz and Boltzmann. Despite its simplicity, this argument has remained almost unknown. We present it in a modern, self-contained and accessible form. The approach constitutes an important link between classical mechanics and statistical mechanics.

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Michele Campisi, Donald H. Kobe. 2009-11-11. Derivation of Boltzmann Principle. https://doi.org/10.1119/1.3298372

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