SearcharxivSearch

arXiv · 1003.3832

Quantum mechanical and information theoretic view on classical glass transitions

Abstract

Using the mapping of the Fokker-Planck description of classical stochastic dynamics onto a quantum Hamiltonian, we argue that a dynamical glass transition in the former must have a precise definition in terms of a quantum phase transition in the latter. At the dynamical level, the transition corresponds to a collapse of the excitation spectrum at a critical point. At the static level, the transition affects the ground state wavefunction: while in some cases it could be picked up by the expectation value of a local operator, in others the order may be non-local, and impossible to be determined with any local probe. Here we propose instead to use concepts from quantum information theory that are not centered around local order parameters, such as fidelity and entanglement measures. We show that for systems derived from the mapping of classical stochastic dynamics, singularities in the fidelity susceptibility translate directly into singularities in the heat capacity of the classical system. In classical glassy systems with an extensive number of metastable states, we find that the prefactor of the area law term in the entanglement entropy jumps across the transition. We also discuss how entanglement measures can be used to detect a growing correlation length that diverges at the transition. Finally, we illustrate how static order can be hidden in systems with a macroscopically large number of degenerate equilibrium states by constructing a three dimensional lattice gauge model with only short-range interactions but with a finite temperature continuous phase transition into a massively degenerate phase.

Explore related subjects

Keep this discovery

BibTeXRIS

Claudio Castelnovo, Claudio Chamon, David Sherrington. 2010-03-19. Quantum mechanical and information theoretic view on classical glass transitions. https://doi.org/10.1103/physrevb.81.184303

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech