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arXiv · 1108.4456

Geometrical frustration in the spin liquid beta'-Me3EtSb[Pd(dmit)2]2 and the valence bond solid Me3EtP[Pd(dmit)2]2

E. P. Scriven·B. J. Powell
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Abstract

We show that the electronic structures of the title compounds predicted by density functional theory (DFT) are well described by tight binding models. We determine the frustration ratio, J'/J, of the Heisenberg model on the anisotropic triangular lattice, which describes the spin degrees of freedom in the Mott insulating phase for a range of Pd(dmit)2 salts. All of the antiferromagnetic materials studied have J'/J < 0.5 or J'/J > 0.9, consistent with predictions for the Heisenberg model. All salts with 0.5 < J'/J < 0.9, where many-body theories find a number of competing ground states, are known, experimentally, to be charge ordered, valence bond solids or spin liquids.

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E. P. Scriven, B. J. Powell. 2012-07-27. Geometrical frustration in the spin liquid beta'-Me3EtSb[Pd(dmit)2]2 and the valence bond solid Me3EtP[Pd(dmit)2]2. https://doi.org/10.1103/physrevlett.109.097206

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