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arXiv · 1109.4956

Theory of dissociative recombination of highly-symmetric polyatomic ions

Nicolas Douguet·Ann E. Orel·Chris H. Greene·Viatcheslav Kokoouline
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Abstract

A general first-principles theory of dissociative recombination is developed for highly-symmetric molecular ions and applied to H$_3$O$^{+}$ and CH$_3^+$, which play an important role in astrophysical, combustion, and laboratory plasma environments. The theoretical cross-sections obtained for the dissociative recombination of the two ions are in good agreement with existing experimental data from storage ring experiments.

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Nicolas Douguet, Ann E. Orel, Chris H. Greene, Viatcheslav Kokoouline. 2011-11-04. Theory of dissociative recombination of highly-symmetric polyatomic ions. https://doi.org/10.1103/physrevlett.108.023202

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