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arXiv · 1201.0902

KxFe2-ySe2 single crystals: Floating-zone growth, Transport and Structural properties

Y. Liu·Z. C. Li·W. P. Liu·G. Friemel·D. S. Inosov·R. E. Dinnebier·Z. J. Li·C. T. Lin
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Abstract

Single crystals of superconducting KxFe2-ySe2 have been grown with the optical floating-zone technique under application of 8 bar of argon pressure. We found that large and high quality single crystals with dimensions of ~\varnothing6 \times 10 mm could be obtained at the termination of the grown ingot through quenching, while the remaining part of the ingot decomposed. As-grown single crystals commonly represent an intergrowth of two sets of the c-axis characterized by slightly different lattice constants. Single crystal of K0.80Fe1.81Se2 shows a superconducting transition at Tc = 31.6 K, leading to a near 100% expulsion of the external magnetic field in magnetization measurements. On the other hand, neutron-diffraction data indicate that superconductivity in the sample coexists with a iron-vacancy superstructure and static antiferromagnetic order. The anisotropic ratio of the upper critical field Hc2 for both H//c and H//ab configurations is \sim3.46.

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Y. Liu, Z. C. Li, W. P. Liu, G. Friemel, D. S. Inosov, R. E. Dinnebier, Z. J. Li, C. T. Lin. 2012-01-04. KxFe2-ySe2 single crystals: Floating-zone growth, Transport and Structural properties. https://doi.org/10.1088/0953-2048%2F25%2F7%2F075001

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