Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · 1212.0971

Far- and mid-infrared spectroscopy of complex organic matter of astrochemical interest: coal, heavy petroleum fractions, and asphaltenes

F. Cataldo·D. A. Garcia-Hernandez·A. Manchado
View original source ↗Read source document ↗Export metadata ↓

Abstract

The coexistence of a large variety of molecular species (i.e., aromatic, cycloaliphatic and aliphatic) in several astrophysical environments suggests that unidentified IR emission (UIE) occurs from small solid particles containing a mix of aromatic and aliphatic structures (e.g., coal, petroleum, etc.), renewing the astronomical interest on this type of materials. A series of heavy petroleum fractions namely DAE, RAE, BQ-1, and asphaltenes derived from BQ-1 were used together with anthracite coal and bitumen as model compounds in matching the band pattern of the emission features of proto-planetary nebulae (PPNe). All the model materials were examined in the mid-infrared (2.5-16.7 um) and for the first time in the far-infrared (16.7-200 um), and the IR bands were compared with the UIE from PPNe. The best match of the PPNe band pattern is offered by the BQ-1 heavy aromatic oil fraction and by its asphaltenes fraction. Particularly interesting is the ability of BQ-1 to match the band pattern of the aromatic-aliphatic C-H stretching bands of certain PPNe, a result which is not achieved neither by the coal model nor by the other petroleum fractions considered here. This study shows that a new interesting molecular model of the emission features of PPNe are asphaltene molecules which are composed by an aromatic core containing 3-4 condensed aromatic rings surrounded by cycloaliphatic (naphtenic) and aliphatic alkyl chains. It is instead shown the weakness of the model involving a mixture of PAHs for modeling the aromatic IR emission bands. The laboratory spectra of these complex organic compounds represent a unique data set of high value for the astronomical community; e.g., they may be compared with the Herschel Space Observatory spectra (~51-220 um) of several astrophysical environments such as (proto-) PNe, H II regions, reflection nebulae, star forming galaxies, and young stellar objects.

Explore related subjects

astro-ph.SRastro-ph.IMphysics.chem-phphysics.space-ph

Keep this discovery

BibTeXRIS

F. Cataldo, D. A. Garcia-Hernandez, A. Manchado. 2012-12-05. Far- and mid-infrared spectroscopy of complex organic matter of astrochemical interest: coal, heavy petroleum fractions, and asphaltenes. https://doi.org/10.1093/mnras/sts558

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Eclipse Properties and Superhump Evolution in the SU UMa-Type Dwarf Nova Z Cha

The advent of large-scale time-domain surveys provides both opportunities and challenges for understanding accretion disk evolution in cataclysmic variables (CVs). Using high-cadence photometry from the Transiting Exoplanet Survey Satellite (TESS), we investigate the eclipsing SU UMa-type dwarf nova Z Cha. Leveraging eclipses as a natural probe, we examine the evolution of the accretion disk through variations in eclipse depth, O--C of eclipse minima, and positive superhump (PSH) amplitude. During superoutbursts, all three quantities exhibit quasi-periodic modulations with a common period of $\sim$2 days, consistent with the precession period of an eccentric disk. We interpret these correlated variations as evidence of an eccentric, precessing disk: O--C traces the periodic shift of the system's brightness center, while eclipse depth and PSH amplitude vary with the orientation of the disk bulge relative to the line of sight. In quiescence (Sectors 13 and 93), PSHs with periods of $\sim$0.0762 days show linearly decreasing amplitudes and periods, indicating gradual shrinkage of the eccentric disk and a slowing precession. Remarkably, a coherent signal with a period of $\sim$0.0729~days ($\epsilon^{-}\approx-0.02$) appears in the same quiescent intervals. This signal may represent negative superhumps (NSHs) coexisting with PSHs, although an orbital sideband of the PSH cannot presently be excluded with the available data. If confirmed as NSHs, their coexistence with PSHs would challenge the classical tilted-disk model, and could be explained by retrograde apsidal precession of an eccentric disk, where the inner disk precesses retrogradely (NSHs) and the outer disk progradely (PSHs); this interpretation remains to be tested by further observations.

astro-ph.SR↗
arXiv2026

Classical Nova V1405 Cas Had $M_{\rm ejecta}$$>$$M_{\rm accreted}$ and so is Unlikely to be a Type Ia Supernova Progenitor

Nova 2021 Cassiopeia (V1405 Cas) was an ordinary J(175) neon nova with the white dwarf mass estimated to be $M_{\rm WD}$=0.60$\pm$0.10 $M_{\odot}$. I found an orbital period of $P$=0.1884 days, and have tracked 20 times of photometric minima from 2013--2025. I measure that $P$ increased from before to after the eruption with $P_{\rm pre}$=0.1883919$\pm$0.0000018 days and $P_{\rm post}$=0.1884043$\pm$0.0000018 days, for $\Delta P$/$P$=66$_{-18}^{+21}$ parts-per-million. With correction for the angular momentum loss by the binary during the eruption, I derive that the nova ejected $M_{\rm ejecta}$=7.5$\times$10$^{-4}$ $M_{\odot}$, with an extreme range of (2.9--40)$\times$10$^{-4}$ $M_{\odot}$. The mass accreted during the previous eruption cycle comes from the trigger mass, and is $M_{\rm accreted}$=(1.6$\pm$0.4)$\times$10$^{-4}$ $M_{\odot}$. V1405 Cas provides counterexamples against five claims about CV evolution that have dominated since the 1980s. First, V1405 Cas has positive $\dot{P}$, and this is contrary to the Magnetic Braking Model. Second, the $\Delta P$ is 20$\times$ too small to allow the system to fade into a hibernation state. Third, $M_{\rm WD}$ is decreasing over time, as shown by $M_{\rm ejecta}$$>$$M_{\rm accreted}$ and by being a neon nova. Fourth, V1405 Cas is not a Type Ia supernova progenitor, for the same reasons. Fifth, the orbital period of V1405 Cas increased by $+$75 ppm from 2013--2025, as a counterexample to the pervasive idea that cataclysmic variables are universally declining in period from evolution. V1405 Cas is the latest of recent measures of $\Delta P$ and $\dot{P}$ for 52 cataclysmic variables and 25 X-ray binaries that have together refuted all five claims.

astro-ph.SR↗
arXiv2026

A prolonged plateau-to-tail transition in the Type II supernova SN2025abyc

We present optical photometric and spectroscopic observations of the Type II supernova SN2025abyc. During the optically thick phase between approximately 10 and 70 d after explosion, its light curves show strongly wavelength-dependent decline rates of approximately 2.7, 2.1, 0.9, and 0.8 mag/100d in the g, c, r, and o bands, respectively. At approximately 70 d, the light curves begin to depart from their nearly linear plateau evolution and gradually transition toward the radioactive tail. A Fermi-Dirac fit to the well-sampled ATLAS o-band light curve yields a transition midpoint of t_PT ~ 100.5d. The interval between the end of the linear plateau and this transition midpoint is approximately 30 d, indicating a prolonged plateau-to-tail transition. This timescale is comparable to those measured for SN2013by, SN2013ej, and SN2014G. Spectroscopically, at +13 d post-explosion, the Halpha profile appears weak and broad, whereas Hbeta and Hgamma display clear P-Cygni profiles. This morphology can be explained by the normal early spectroscopic evolution of SNe II, although partial filling of the Halpha absorption trough by emission associated with circumstellar interaction cannot be excluded. SN2025abyc otherwise follows the general photospheric velocity evolution of SNe II, while remaining toward the high-velocity side of the comparison distribution in Halpha, Hbeta, and FeII. Exploratory light-curve modelling suggests a synthesized Ni mass of approximately 0.03-0.04 solar mass. We suggest that the extended circumstellar environment, Ni distribution, and hydrogen-envelope structure could all play a role in shaping the observed light-curve evolution, particularly the prolonged plateau-to-tail transition.

astro-ph.SR↗