A Novel Construction of Complex-valued Gaussian Processes with Arbitrary Spectral Densities and its Application to Excitation Energy Transfer

Xin Chen; Jianshu Cao; Robert Silbey

doi:10.1063/1.4808377

Home/Archive/arXiv

arXiv · 1304.3143

A Novel Construction of Complex-valued Gaussian Processes with Arbitrary Spectral Densities and its Application to Excitation Energy Transfer

Xin Chen·Jianshu Cao·Robert Silbey

View original source ↗Read source document ↗Export metadata ↓

Abstract

The recent experimental discoveries about excitation energy transfer (EET) in light harvesting antenna (LHA) attract a lot of interest. As an open non-equilibrium quantum system, the EET demands more rigorous theoretical framework to understand the interaction between system and environment and therein the evolution of reduced density matrix. A phonon is often used to model the fluctuating environment and convolutes the reduced quantum system temporarily. In this paper, we propose a novel way to construct complex-valued Gaussian processes to describe thermal quantum phonon bath exactly by converting the convolution of influence functional into the time correlation of complex Gaussian random field. Based on the construction, we propose a rigorous and efficient computational method, the covariance decomposition (CD) and conditional propagation scheme, to simulate the temporarily entangled reduced system. The new method allows us to study the non-Markovian effect without perturbation under the influence of different spectral densities of the linear system-phonon coupling coefficients. Its application in the study of EET in the Fenna-Matthews-Olson (FMO) model Hamiltonian under four different spectral densities is discussed. Since the scaling of our algorithm is linear due to its Monte Carlo nature, the future application of the method for large LHA systems is attractive. In addition, this method can be used to study the effect of correlated initial condition on the reduced dynamics in the future.

Explore related subjects

cond-mat.stat-mech physics.chem-ph

Keep this discovery

BibTeX RIS

Xin Chen, Jianshu Cao, Robert Silbey. 2013-04-10. A Novel Construction of Complex-valued Gaussian Processes with Arbitrary Spectral Densities and its Application to Excitation Energy Transfer. https://doi.org/10.1063/1.4808377

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech↗

arXiv2026

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech↗

arXiv2026

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech↗