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arXiv · 1310.5580

How many is different? Answer from ideal Bose gas

Jeong-Hyuck Park
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Abstract

How many $\mathrm{H_{2}O}$ molecules are needed to form water? While the precise answer is not known, it is clear that the answer should be a finite number rather than infinity. We revisit with care the ideal Bose gas confined in a cubic box which is discussed in most statistical physics textbooks. We show that the isobar of the ideal gas zigzags on the temperature-volume plane featuring a `boiling-like' discrete phase transition, provided the number of particles is equal to or greater than a particular value: 7616. This demonstrates for the first time how a finite system can feature a mathematical singularity and realize the notion of `Emergence', without resorting to the thermodynamic limit.

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BibTeXRIS

Jeong-Hyuck Park. 2013-10-21. How many is different? Answer from ideal Bose gas. https://doi.org/10.1088/1742-6596/490/1/012018

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