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arXiv · 1312.6240

Molecular-Level Switching of Polymer/Nanocrystal Non-Covalent Interactions and Application in Hybrid Solar Cells

Carlo Giansante·Rosanna Mastria·Giovanni Lerario·Luca Moretti·Ilka Kriegel·Francesco Scotognella·Guglielmo Lanzani·Sonia Carallo·Marco Esposito·Mariano Biasiucci·Aurora Rizzo·Giuseppe Gigli
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Abstract

Hy brid composites obtained upon blending conjugated polymers and colloidal inorganic semiconductor nanocrystals are regarded as attractive photo-active materials for optoelectronic applications. Here we demonstrate that tailoring nanocrystal surface chemistry permits to exert control on non-covalent bonding and electronic interactions between organic and inorganic components. The pendant moieties of organic ligands at the nanocrystal surface do not merely confer colloidal stability while hindering charge separation and transport, but drastically impact morphology of hybrid composites during formation from blend solutions. The relevance of our approach to photovoltaic applications is demonstrated for composites based on poly(3-hexylthiophene) and Pbs nanocrystals, considered as inadequate before the submission of this manuscript, which enable the fabrication of hybrid solar cells displaying a power conversion efficiency that reaches 3 %. Upon (quasi)steady-state and time-resolved analisys of the photo-induced processes in the nanocomposites and their organic and inorganic components, we ascertained that electron transfer occurs at the hybrid interface yielding long-lived separated charge carriers, whereas interfacial hole transfer appears slow. Here we provide a reliable alternative aiming at gaining control over macroscopic optoelectronic properties of polymer/nanocrystal composites by acting at the molecular-level via ligands' pendant moieties, thus opening new possibilities towards efficient solution-processed hybrid solar cells.

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Carlo Giansante, Rosanna Mastria, Giovanni Lerario, Luca Moretti, Ilka Kriegel, Francesco Scotognella, Guglielmo Lanzani, Sonia Carallo, Marco Esposito, Mariano Biasiucci, Aurora Rizzo, Giuseppe Gigli. 2013-12-21. Molecular-Level Switching of Polymer/Nanocrystal Non-Covalent Interactions and Application in Hybrid Solar Cells. https://doi.org/10.1002/adfm.201401841

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