SearcharxivSearch

arXiv · 1403.4771

Non-equilibrium ensemble inequivalence and density large deviations in the ABC model

Abstract

We consider the one-dimensional driven ABC model under particle-conserving and particle-non-conserving processes. Two limiting cases are studied: (a) the rates of the non-conserving processes are vanishingly slow compared with the conserving processes in the thermodynamic limit and (b) the two rates are comparable. For case (a) we provide a detailed analysis of the phase diagram and the large deviations function of the overall density, G(r). The phase diagram of the non-conserving model, derived from G(r), is found to be different from the conserving one. This difference, which stems from the non-convexity of G(r), is analogous to ensemble inequivalence found in equilibrium systems with long-range interactions. An outline of the analysis of case (a) was given in an earlier letter. For case (b) we show that unlike the conserving model, the non-conserving model exhibits a moving density profile in the steady-state with a velocity that remains finite in the thermodynamic limit. Moreover, in contrast with case (a), the critical lines of the conserving and non-conserving models do not coincide. These are new features which are present only when the rates of the conserving and non-conserving processes are comparable. In addition, we analyze G(r) in case (b) using macroscopic fluctuations theory. Much of the derivation presented in this paper is applicable to any driven-diffusive system coupled to an external particle-bath via a slow dynamics.

Explore related subjects

Keep this discovery

BibTeXRIS

Or Cohen, David Mukamel. 2014-03-19. Non-equilibrium ensemble inequivalence and density large deviations in the ABC model. https://arxiv.org/abs/1403.4771

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech