Ultrafast Liquid Water Transport Through Graphene-Based Nanochannels Measured by Isotope Labelling

Pengzhan Sun; He Liu; Kunlin Wang; Minlin Zhong; Dehai Wu; Hongwei Zhu

doi:10.1039/c4cc10103k

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arXiv · 1405.4722

Ultrafast Liquid Water Transport Through Graphene-Based Nanochannels Measured by Isotope Labelling

Pengzhan Sun·He Liu·Kunlin Wang·Minlin Zhong·Dehai Wu·Hongwei Zhu

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Abstract

Graphene-based laminates, with ultralong and tortuous nanocapillaries formed by simply stacking graphene flakes together, have great promises in filtration and separation. However, the information on liquid water trans-membrane permeation is lacking, which is the most fundamental problem and of crucial importance in solution-based mass transport. Here, based on isotope labelling, we investigate the liquid water transportation through graphene-based nanocapillaries under no external hydrostatic pressures. Liquid water can afford an unimpeded permeation through graphene-based nanochannels with a diffusion coefficient 4~5 orders of magnitude larger than through sub-micrometer-sized polymeric channels. When dissolving ions in sources, the diffusion coefficient of ions through graphene channels lies in the same order of magnitude as water, while the ion diffusion is faster than water, indicating that the ions are mainly transported by fast water flows and the delicate interactions between ions and nanocapillary walls also take effect in the accelerated ion transportation.

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Pengzhan Sun, He Liu, Kunlin Wang, Minlin Zhong, Dehai Wu, Hongwei Zhu. 2014-05-19. Ultrafast Liquid Water Transport Through Graphene-Based Nanochannels Measured by Isotope Labelling. https://doi.org/10.1039/c4cc10103k

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