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arXiv · 1407.0277

Virial expansion and condensation with a new generating function

Vishnu M. Bannur
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Abstract

Mayer's convergence method for virial expansion and condensation is studied using a new generating function for canonical partition function, which directly depends on irreducible cluster integral, $\beta_k$, unlike Mayer's work where it depends on reducible cluster integral, $b_l$. The virial expansion, criteria for it's validity and criteria for condensation, etc. are derived from our generating function. All earlier Mayer's results are obtained from this new generating function.

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Vishnu M. Bannur. 2014-06-30. Virial expansion and condensation with a new generating function. https://doi.org/10.1016/j.physa.2014.10.053

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