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arXiv · 1502.04762

Effect of Sn-substitution on Thermoelectric Properties of Copper-based Sulfide, Famatinite Cu3SbS4

Yosuke Goto·Yuki Sakai·Yoichi Kamihara·Masanori Matoba
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Abstract

Copper-based sulfide is an attractive material for Earth-abundant thermoelectrics. In this study, we demonstrate the effect of Sn-substitution on the electrical and thermal transport properties of fematinite Cu3SbS4 from 300 to 573 K. The carrier concentration is controlled in the range from 4 \times 10^18 to 8 \times 10^20 cm^-3 by Sn-substitution. The density-of-states effective mass is found to be ~3.0 me, assuming the single parabolic band model. The direct-type optical band gap is ~0.9 eV, which is consistent with the density functional theory calculation. The dimensionless figure of merit reaches 0.1 for Sn-doped samples at 573 K.

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Yosuke Goto, Yuki Sakai, Yoichi Kamihara, Masanori Matoba. 2015-02-17. Effect of Sn-substitution on Thermoelectric Properties of Copper-based Sulfide, Famatinite Cu3SbS4. https://doi.org/10.7566/jpsj.84.044706

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