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arXiv · 1503.09141

Microscopic theory for electrocaloric effects in planar double layer systems

Rajeev Kumar·Jyoti P. Mahalik·Evgheni Strelcov·Alexander Tselev·Bradley S. Lokitz·Sergei. V. Kalinin·Bobby G. Sumpter
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Abstract

We present a field theory approach to study changes in local temperature due to an applied electric field (the electrocaloric effect) in electrolyte solutions. Steric effects and a field-dependent dielectric function are found to be of paramount importance for accurate estimations of the electrocaloric effect. Interestingly, electrolyte solutions are found to exhibit negative electrocaloric effects. Overall, our results point toward using fluids near room temperature with low heat capacity and high salt concentration for enhanced electrocalorics.

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Rajeev Kumar, Jyoti P. Mahalik, Evgheni Strelcov, Alexander Tselev, Bradley S. Lokitz, Sergei. V. Kalinin, Bobby G. Sumpter. 2015-03-31. Microscopic theory for electrocaloric effects in planar double layer systems. https://arxiv.org/abs/1503.09141

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