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arXiv · 1507.01947

Microscopic dynamics of supercooled liquids from first principles

Liesbeth M. C. Janssen·David R. Reichman
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Abstract

Glasses are solid materials whose constituent atoms are arranged in a disordered manner. The transition from a liquid to a glass remains one of the most poorly understood phenomena in condensed matter physics, and still no fully microscopic theory exists that can describe the dynamics of supercooled liquids in a quantitative manner over all relevant time scales. Here we present such a theoretical framework that yields near-quantitative accuracy for the time-dependent correlation functions of a supercooled system over a broad density range. Our approach requires only simple static structural information as input and is based entirely based on first principles. Owing to this first-principles nature, the framework offers a unique platform to study the relation between structure and dynamics in glass-forming matter, and paves the way towards a systematically correctable and ultimately fully quantitative theory of microscopic glassy dynamics.

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BibTeXRIS

Liesbeth M. C. Janssen, David R. Reichman. 2015-07-07. Microscopic dynamics of supercooled liquids from first principles. https://doi.org/10.1103/physrevlett.115.205701

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