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arXiv · 1509.02240

Probing Scalar Coupling Differences via Long-Lived Singlet States

Stephen J. DeVience·Ronald L. Walsworth·Matthew S. Rosen
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Abstract

We probe small scalar coupling differences via the coherent interactions between two nuclear spin singlet states in organic molecules. We show that the spin-lock induced crossing (SLIC) technique enables the coherent transfer of singlet order between one spin pair and another. The transfer is mediated by the difference in cis and trans vicinal J couplings among the spins. By measuring the transfer rate, we calculate a J coupling difference of $8 \pm 2$ mHz in phenylalanine-glycine-glycine and $2.57 \pm 0.04$ Hz in glutamate. We also characterize a coherence between two singlet states in glutamate, which may enable the creation of a long-lived quantum memory.

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Stephen J. DeVience, Ronald L. Walsworth, Matthew S. Rosen. 2015-09-08. Probing Scalar Coupling Differences via Long-Lived Singlet States. https://doi.org/10.1016/j.jmr.2015.12.003

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