Explicit exponential convergence to equilibrium for nonlinear reaction-diffusion systems with detailed balance condition

Abstract

The convergence to equilibrium of mass action reaction-diffusion systems arising from networks of chemical reactions is studied. The considered reaction networks are assumed to satisfy the detailed balance condition and have no boundary equilibria. We propose a general approach based on the so-called entropy method, which is able to quantify with explicitly computable rates the decay of an entropy functional in terms of an entropy entropy-dissipation inequality based on the totality of the conservation laws of the system. As a consequence follows convergence to the unique detailed balance equilibrium with explicitly computable convergence rates. The general approach is further detailed for two important example systems: a single reversible reaction involving an arbitrary number of chemical substances and a chain of two reversible reactions arising from enzyme reactions.