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arXiv · 1602.05687

Hole-doping-induced melting of spin-state ordering in PrBaCo2O5.5+x

Ping Miao·Xiaohuan Lin·Sanghyun Lee·Yoshihisa Ishikawa·Shuki Torii·Masao Yonemura·Tetsuro Ueno·Nobuhito Inami·Kanta Ono·Yinxia Wang·Takashi Kamiyama
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Abstract

The layered perovskite cobaltite RBaCo$_2$O$_{5.5}$ (R: rare-earth elements or Yttrium) exhibits an abrupt temperature-induced metal$-$insulator transition (MIT) and has been attributed to spin-state ordering (SSO) of Co$^{3+}$ ions. Here we investigated the hole doping member of PrBaCo$_2$O$_{5.5+x}$ ($0 \le x \le 0.24$) with multiple techniques. The analysis on crystal and magnetic structures by electron and neutron diffraction confirm the SSO in the insulating phase of undoped PrBaCo$_2$O$_{5.5}$, which is melted by increasing the temperature across the MIT. In addition, we discovered that hole doping to PrBaCo$_2$O$_{5.5}$ also melts the SSO in conjunction with an insulator-metal transition. The experimental results from electron/neutron diffraction and soft x-ray absorption spectroscopy (XAS) all lead to the conclusion that hole-doping induced MIT occurs is in the same manner as the temperature-induced MIT. Therefore, we propose a unified mechanism that dominates the temperature- and hole-doping-induced MITs in the PrBaCo$_2$O$_{5.5+x}$ system. Specifically, this mechanism involves symmetry breaking coupled with a SSO in the paramagnetic phase.

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Ping Miao, Xiaohuan Lin, Sanghyun Lee, Yoshihisa Ishikawa, Shuki Torii, Masao Yonemura, Tetsuro Ueno, Nobuhito Inami, Kanta Ono, Yinxia Wang, Takashi Kamiyama. 2016-12-19. Hole-doping-induced melting of spin-state ordering in PrBaCo2O5.5+x. https://doi.org/10.1103/physrevb.95.125123

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