arXiv subjects

Yoshihisa Ishikawa

Publications and source records attributed to Yoshihisa Ishikawa.

6 recordsLinked to original sources

arXiv2026

Highly fluctuating double-$q$ magnetic order in the van der Waals metal CeTe$_3$

CeTe$_3$ is a van der Waals antiferromagnet composed of magnetic [CeTe]$^+$ layers coupled to highly conducting Te$^{0.5-}$ square nets. Its simple quasi-two-dimensional electronic structure and cleavable nature make it an appealing platform for exploring correlated magnetism in reduced dimensions. To clarify the nature of its low-temperature state, we performed single-crystal neutron diffraction down to 0.3 K, complemented by scanning tunneling microscopy. A magnetic transition near 1.5 K gives rise to incommensurate Bragg peaks at $q_{\pm}\sim(\pm0.17,0,0.31)$, consistent with a double-$q$ magnetic order whose moments are predominantly aligned along the $c$ axis. The strongly reduced ordered moment is consistent with enhanced quantum fluctuations driven by $c$-$f$ hybridization, while the deviation of the propagation vectors from simple nesting suggests a coupling to residual charge-density-wave instabilities of the quasi-one-dimensional Te-derived bands. These results indicate that CeTe$_3$ hosts a correlated magnetic ground state where spin and itinerant charge degrees of freedom are intimately linked in the van der Waals limit.

cond-mat.str-el↗

arXiv2024

Toward the theoretically observable limit of electron density distribution by single-crystal synchrotron X-ray diffraction: The case of orbitally ordered Ti-3d^1 in YTiO_3

The theoretically observable limit of electron density distribution by single-crystal X-ray diffraction is discussed. When F_{orb} and δF are defined as, respectively, the partial structure factor for an orbital and the deviation of the observed F from the true F, the accuracy of electron density attributable to F_{orb} is chiefly determined by the number of reflections satisfying the condition F_{orb}/F > δF/F. Since F_{orb}/F, which is generally small for crystals with large F(0,0,0), is constant under a given set of experimental conditions, δF/F must be reduced to increase the number of reflections satisfying F_{orb}/F > δF/F. The present paper demonstrates how to reduce δF mathematically and experimentally, and the following topics are covered: the Poisson statistics, accumulation of errors in the data collection and reduction procedure, multiple diffraction, conversion error from F^2 to F in refinement programs, which is unavoidable when the input quantities have different dimension from F, weighting of reflections, and tips. For demonstration, observation of the electron density of the Ti-3d^1 orbital in YTiO_3 by synchrotron single-crystal X-ray diffraction is presented.

cond-mat.mtrl-sci↗

arXiv2023

Chiral Dirac fermion in a collinear antiferromagnet

In a Dirac semimetal, the massless Dirac fermion has zero chirality, leading to surface states connected adiabatically to a topologically trivial surface state as well as vanishing anomalous Hall effect (AHE). Recently, it is predicted that in the nonrelativistic limit of certain collinear antiferromagnets, there exists a type of chiral Dirac-like fermion, whose dispersion manifests four-fold degenerate crossing points formed by spin-degenerate linear bands, with topologically protected Fermi arcs. Such unconventional chiral fermion, protected by a hidden SU(2) symmetry in the hierarchy of an enhanced crystallographic group, namely spin space group, is not experimentally verified yet. Here, by angle-resolved photoemission spectroscopy measurements, we reveal the surface origin of the electron pocket at the Fermi surface in collinear antiferromagnet CoNb3S6. Combining with neutron diffraction and first-principles calculations, we suggest a multidomain collinear AFM configuration, rendering the the existence of the Fermi-arc surface states induced by chiral Dirac-like fermions. Our work provides spectral evidence of the chiral Dirac-like fermion caused by particular spin symmetry in CoNb3S6, paving an avenue for exploring new emergent phenomena in antiferromagnets with unconventional quasiparticle excitations.

cond-mat.mtrl-sci↗

arXiv2020

Origin of magnetovolume effect in a cobaltite

The layered perovskite PrBaCo2O5.5+x demonstrates a strong negative thermal expansion (NTE) which holds potential for being fabricated into composites with zero thermal expansion. The NTE was found to be intimately associated with the spontaneous magnetic ordering, known as magnetovolume effect (MVE). Here we report with compelling evidences that the continuous-like MVE in PrBaCo2O5.5+x is intrinsically of discontinuous character, originating from an magnetoelectric transition from an antiferromagnetic insulating large-volume (AFILV) phase to a ferromagnetic metallic small-volume (FMSV) phase. Furthermore, the magnetoelectric effect (ME) shows high sensitivity to multiple external stimuli such as temperature, carrier doping, hydrostatic pressure, magnetic field etc. In contrast to the well-known ME such as colossal magnetoresistance and multiferroic effect which involve symmetry breaking of crystal structure, the ME in the cobaltite is purely isostructural. Our discovery provides a new pathway to realizing the ME as well as the NTE, which may find applications in new techniques.

cond-mat.str-el↗

arXiv2016

Hole-doping-induced melting of spin-state ordering in PrBaCo2O5.5+x

The layered perovskite cobaltite RBaCo$_2$O$_{5.5}$ (R: rare-earth elements or Yttrium) exhibits an abrupt temperature-induced metal$-$insulator transition (MIT) and has been attributed to spin-state ordering (SSO) of Co$^{3+}$ ions. Here we investigated the hole doping member of PrBaCo$_2$O$_{5.5+x}$ ($0 \le x \le 0.24$) with multiple techniques. The analysis on crystal and magnetic structures by electron and neutron diffraction confirm the SSO in the insulating phase of undoped PrBaCo$_2$O$_{5.5}$, which is melted by increasing the temperature across the MIT. In addition, we discovered that hole doping to PrBaCo$_2$O$_{5.5}$ also melts the SSO in conjunction with an insulator-metal transition. The experimental results from electron/neutron diffraction and soft x-ray absorption spectroscopy (XAS) all lead to the conclusion that hole-doping induced MIT occurs is in the same manner as the temperature-induced MIT. Therefore, we propose a unified mechanism that dominates the temperature- and hole-doping-induced MITs in the PrBaCo$_2$O$_{5.5+x}$ system. Specifically, this mechanism involves symmetry breaking coupled with a SSO in the paramagnetic phase.

cond-mat.str-el↗

arXiv2014

Bipartite magnetic parent phases in the iron-oxypnictide superconductor

High-temperature (high-$T_{\rm c}$) superconductivity appears as a consequence of the carrier-doping of an undoped parent compound exhibiting antiferromagnetic order; thereby, ground-state properties of the parent compound are closely relevant to the superconducting state. On the basis of the concept, a spin-fluctuation has been addressed as an origin of pairing of the superconducting electrons in cuprates. Whereas, there is growing interest in the pairing mechanism such as an unconventional spin-fluctuation or an advanced orbital-fluctuation due to the characteristic multi-orbital system in iron-pnictides. Here, we report the discovery of an antiferromagnetic order as well as a unique structural transition in electron-overdoped LaFeAsO$_{1-x}$H$_x$ ($x$ ~ 0.5), whereby another parent phase was uncovered, albeit heavily doped. The unprecedented two-dome superconducting phases observed in this material can be interpreted as a consequence of the carrier-doping starting from the original at $x\sim0$ and advanced at $x\sim0.5$ parent phases toward the intermediate region. The bipartite parent phases with distinct physical properties in the second magnetic phase provide us with an interesting example to illustrate the intimate interplay among the magnetic interaction, structural change and orbital degree of freedom in iron-pnictides.

cond-mat.str-el↗