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arXiv · 1611.09951

A High Efficiency Aluminum-Ion Battery Using an AlCl3-Urea Ionic Liquid Analogue Electrolyte

Michael Angell·Chun-Jern Pan·Youmin Rong·Chunze Yuan·Meng-Chang Lin·BingJoe Hwang·Hongjie Dai
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Abstract

In recent years, impressive advances in harvesting renewable energy have led to pressing demand for the complimentary energy storage technology. Here, a high coulombic efficiency (~ 99.7%) Al battery is developed using earth-abundant aluminum as the anode, graphite as the cathode, and a cheap ionic liquid analogue electrolyte made from a mixture of AlCl3 and urea in 1.3 : 1 molar ratio. The battery displays discharge voltage plateaus around 1.9 V and 1.5 V (average discharge = 1.73 V) and yielded a specific cathode capacity of ~73 mAh g-1 at a current density of 100 mA g-1 (~ 1.4 C). High coulombic efficiency over a range of charge-discharge rates and stability over ~150-200 cycles was easily demonstrated. In-situ Raman spectroscopy clearly showed chloroaluminate anion intercalation/deintercalation of graphite in the cathode side during charge/discharge and suggested the formation of a stage 2 graphite intercalation compound when fully charged. Raman spectroscopy and nuclear magnetic resonance suggested the existence of AlCl4-, Al2Cl7- anions, and [AlCl2. (urea)n]+ cations in the urea/AlCl3 electrolyte when an excess of AlCl3 was present. Aluminum deposition therefore proceeded through two pathways, one involving Al2Cl7- anions and the other involving [AlCl2.(urea)n]+ cations. This battery is a promising prospect for a future high performance, low cost energy storage device.

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Michael Angell, Chun-Jern Pan, Youmin Rong, Chunze Yuan, Meng-Chang Lin, BingJoe Hwang, Hongjie Dai. 2016-11-30. A High Efficiency Aluminum-Ion Battery Using an AlCl3-Urea Ionic Liquid Analogue Electrolyte. https://doi.org/10.1073/pnas.1619795114

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