Transition rates and radiative lifetimes of Ca I

Yanmei Yu; Andrei Derevianko

doi:10.1016/j.adt.2017.03.002

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arXiv · 1702.03473

Transition rates and radiative lifetimes of Ca I

Yanmei Yu·Andrei Derevianko

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Abstract

We tabulate spontaneous emission rates for all possible 811 electric-dipole-allowed transitions between the 75 lowest-energy states of Ca I. These involve the $4sns$ ($n=4-8$), $4snp$ ($n=4-7$), $4snd$ ($n=3-6$), $4snf$ ($n=4-6$), $4p^2$, and $3d4p$ electronic configurations. We compile the transition rates by carrying out ab initio relativistic calculations using the combined method of configuration interaction and many-body perturbation theory. The results are compared to the available literature values. The tabulated rates can be useful in various applications, such as optimizing laser cooling in magneto-optical traps, estimating various systematic effects in optical clocks and evaluating static or dynamic polarizabilities and long-range atom-atom interaction coefficients and related atomic properties.

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Yanmei Yu, Andrei Derevianko. 2017-02-12. Transition rates and radiative lifetimes of Ca I. https://doi.org/10.1016/j.adt.2017.03.002

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