arXiv subjects

Yanmei Yu

Publications and source records attributed to Yanmei Yu.

7 recordsLinked to original sources

arXiv2025

Relativistic Calculations of Energy Levels, Field Shift Factors, and Polarizabilities of Mercury and Copernicium

Mercury (Hg) and superheavy element copernicium (Cn) are investigated using equation-of-motion relativistic coupled-cluster (EOM-RCC) and configuration interaction plus many-body perturbation theory (CI+MBPT) methods. Key atomic properties including ionization potentials (IP), excitation energies (EEs), isotope field shift factors (F), and static electric dipole polarizabilities ({\alpha}) are calculated for ground and low-lying excited states. To evaluate the theoretical accuracy, calculations for both Hg and Cn are performed, with experimental data of Hg serving as benchmarks. Furthermore, basis set dependence has been systematically evaluated in the EOM-RCC calculations, with corresponding uncertainty estimates having been provided. The calculated atomic properties could provide valuable insights into the electronic structure and chemical behavior of superheavy elements.

physics.atom-ph↗

arXiv2025

Theoretical study of transition matrix elements in cadmium for vacuum-ultraviolet generation in $^{229}$Th nuclear clock applications

The relativistic Fock-space coupled-cluster methods are applied to the cadmium atom. A large number of transition energies and matrix elements are calculated for the $5s^{2}\:$$ ^{1}S \to 5snp\: ^{1,3} P^{o}$, $5s6s\: ^{1}S \to 5snp\: ^{1,3} P^{o}$ and $5s5d\: ^{1}D \to 5snp\: ^{1,3} P^{o}$ transitions for a wide range of $p$ states accounting for relativistic and electron-correlation effects. The results obtained within two different approaches (Fock-space coupled cluster and configuration interaction) are compared with available experimental and theoretical data. Good agreement is found between the two methods for transitions involving low-lying excited $p$-states, whereas for high-lying states, the discrepancy becomes large. The calculated values are used to determine the third-order nonlinear susceptibility of cadmium vapor, with an agreement within 5\% between the different methods. The results of the present computations support the feasibility of generating vacuum ultraviolet light in Cd vapor via a four-wave mixing process for the spectroscopy of $^{229}$Th isomer transition.

physics.atom-ph↗

arXiv2025

Precision determination of the excited-state hyperfine splitting of Cadmium ions

Precision determination of the hyperfine splitting of cadmium ions is essential to study space-time variation of fundamental physical constants and isotope shifts. In this work, we present the precision frequency measurement of the excited-state $^2{P}_{3/2}$ hyperfine splitting of $^{111,113}\mathrm{Cd}^+$ ions using the laser-induced fluorescence technique. By introducing the technology of sympathetic cooling and setting up free-space beat detection unit based on the optical comb, the uncertainties are improved to 14.8 kHz and 10.0 kHz, respectively, two orders of magnitude higher than the reported results from the linear transformation of isotope shifts. The magnetic dipole constants $A_{P_{3/2}}$ of $^{111}\mathrm{Cd}^+$ and $^{113}\mathrm{Cd}^+$ are estimated to be 395 938.8(7.4) kHz and 411 276.0(5.0) kHz, respectively. The difference between the measured and theoretical hyperfine structure constants indicates that more physical effects are required to be considered in the theoretical calculation, and provides critical data for the examination of deviation from King-plot linearity in isotope shifts.

physics.atom-ph↗

arXiv2025

Determination of Land\'{e} $g_J$ factor and Zeeman coefficients in ground-state $^{171}$Yb$^+$ and their applications to quantum frequency standards

We report the determination of the Land\'{e} $g_J$ factor and Zeeman coefficients for the ground-state of $^{171}$Yb$^+$, relevant to microwave quantum frequency standards (QFSs). The $g_J$ factor is obtained by using two independent methods: multiconfiguration Dirac-Hartree-Fock and multireference configuration interaction, yielding a consistent value of 2.002615(70). The first- and second-order Zeeman coefficients are determined as 14,010.78(49) Hz/$\mu$T and 31.0869(22) mHz/$\mu$T$^2$, respectively, based on the calculated $g_J$ factor. These coefficients enable reduced magnetic-field-induced uncertainties, improving the accuracy of the $^{171}$Yb$^+$ microwave QFSs. The results reported in this work also offer potential for improved constraints on variations in fundamental constants through frequency comparisons, and advancing trapped-ion quantum computers based on the ground-state hyperfine splitting of $^{171}$Yb$^+$.

physics.atom-ph↗

arXiv2024

Proposal for the generation of continuous-wave vacuum ultraviolet laser light for Th-229 isomer precision spectroscopy

We propose to generate continuous-wave vacuum ultraviolet (VUV) laser light at 148.4 nm using four-wave mixing in cadmium vapor for precision spectroscopy of the Th-229 isomer transition. Due to the large transition matrix elements of cadmium, the readily accessible wavelengths for the incident laser beams, and the high coherence of the four-wave mixing process, over 30 $\mu$W of VUV power can be generated with a narrow linewidth. This development paves the way for coherently driving the Th-229 isomer transition and developing the nuclear optical clock.

physics.atom-ph↗

arXiv2017

Transition rates and radiative lifetimes of Ca I

We tabulate spontaneous emission rates for all possible 811 electric-dipole-allowed transitions between the 75 lowest-energy states of Ca I. These involve the $4sns$ ($n=4-8$), $4snp$ ($n=4-7$), $4snd$ ($n=3-6$), $4snf$ ($n=4-6$), $4p^2$, and $3d4p$ electronic configurations. We compile the transition rates by carrying out ab initio relativistic calculations using the combined method of configuration interaction and many-body perturbation theory. The results are compared to the available literature values. The tabulated rates can be useful in various applications, such as optimizing laser cooling in magneto-optical traps, estimating various systematic effects in optical clocks and evaluating static or dynamic polarizabilities and long-range atom-atom interaction coefficients and related atomic properties.

physics.atom-ph↗

arXiv2017

Improved magneto-optical trapping of Ca

We investigate the limiting factors in the standard implementation of the Ca magneto-optical trap. We find that intercombination transitions from the 4s5p 1P1 state used to repump electronic population from the 3d4s 1D2 state severely reduce the trap lifetime. We explore seven alternative repumping schemes theoretically and investigate five of them experimentally. We find all five of these schemes yield a significant increase in trap lifetime and consequently improve the number of atoms and peak atom density by as much as ~20x and ~6x, respectively. One of these transitions, at 453 nm, is shown to approach the fundamental limit for a Ca magneto-optical trap with repumping only from the 3d4s 1D2 state, yielding a trap lifetime of ~5 s.

physics.atom-ph↗