Equation of state and optical properties of shock-compressed C:H:N:O molecular mixtures

Abstract

Water, ethanol, and ammonia are the key components of the mantles of Uranus and Neptune. To improve structure and evolution models and give an explanation of the magnetic fields and luminosities of the icy giants, those components need to be characterised at planetary conditions (some Mbar and a few $10^3$ K). Those conditions are typical of the Warm Dense Matter regime, which exhibits a rich phase diagram, with the coexistence of many states of matter and a large variety of chemical processes. H$_2$O, C:H:O, and C:H:N:O mixtures have been compressed up to 2.8 Mbar along the principal Hugoniot using laser-driven decaying shocks. The experiments were performed at the GEKKO XII and LULI 2000 laser facilities using standard optical diagnostics (Doppler velocimetry and pyrometry) to characterise equation of state and optical reflectivity of the shocked states. The results show that H$_2$O and the C:H:N:O mixture share the same equation of state with a density scaling, while the reflectivity behaves differently by what concerns both the onset pressures and the saturation values. The reflectivity measurement at two frequencies allows to estimate the conductivity and the complex refractive index using a Drude model.