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arXiv · 1805.01601

Evolution of Magnetic and Orbital Properties in the Magnetically-Diluted A-Site Spinel Cu$_{1-x}$Zn$_x$Rh$_2$O$_4$

A. V. Zakrzewski·S. Gangopadhyay·A. A. Aczel·S. Calder·T. J. Williams·G. J. MacDougall
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Abstract

In frustrated spinel antiferromagnets, dilution with non-magnetic ions can be a powerful strategy for probing unconventional spin states or uncovering interesting phenomena. Here, we present X-ray, neutron scattering and thermodynamic studies of the effects of magnetic dilution of the tetragonally-distorted A-site spinel antiferromagnet, CuRh$_2$O$_4$, with non-magnetic Zn$^{2+}$ ions. Our data confirm the helical spin order recently identified at low-temperatures in this material, and further demonstrate a systematic suppression of the associated Néel temperature with increasing site dilution towards a continuous transition with critical doping of $x_{spin} \sim 0.44$. Interestingly, this critical doping is demonstrably distinct from a second structural critical point at $x_{JT} \sim 0.6$, which is consistent with the suppression of orbital order on the A-site through a classical percolative mechanism. This anomalously low value for $x_{spin}$ is confirmed via multiple measurements, and is inconsistent with predictions of classical percolation theory, suggesting that the spin transition in this material is driven by an enhancement of pre-existing spin fluctuations with weak dilution.

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A. V. Zakrzewski, S. Gangopadhyay, A. A. Aczel, S. Calder, T. J. Williams, G. J. MacDougall. 2018-06-02. Evolution of Magnetic and Orbital Properties in the Magnetically-Diluted A-Site Spinel Cu$_{1-x}$Zn$_x$Rh$_2$O$_4$. https://doi.org/10.1103/physrevb.97.214411

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