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arXiv · 1805.09130

Noncovalent Functionalization of Black Phosphorus

Gonzalo Abellán·Vicent Lloret·Udo Mundloch·Mario Marcia·Christian Neiss·Andreas Görling·Maria Varela·Frank Hauke·Andreas Hirsch
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Abstract

The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other hand, the non-covalent interaction of BP with perylene diimide is mainly due to van-der-Waals interactions but also leads to a considerable stabilization of the BP flakes against oxygen degradation.

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Gonzalo Abellán, Vicent Lloret, Udo Mundloch, Mario Marcia, Christian Neiss, Andreas Görling, Maria Varela, Frank Hauke, Andreas Hirsch. 2018-05-04. Noncovalent Functionalization of Black Phosphorus. https://doi.org/10.1002/anie.201604784

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