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arXiv · 1811.09202

Ensemble dependence of Critical Casimir Forces in Films with Dirichlet Boundary Conditions

Christian M. Rohwer·Alessio Squarcini·Oleg Vasilyev·S. Dietrich·Markus Gross
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Abstract

In a recent study [Phys. Rev. E \textbf{94}, 022103 (2016)] it has been shown that, for a fluid film subject to critical adsorption, the resulting critical Casimir force (CCF) may significantly depend on the thermodynamic ensemble. Here, we extend that study by considering fluid films within the so-called ordinary surface universality class. We focus on mean-field theory, within which the OP profile satisfies Dirichlet boundary conditions and produces a nontrivial CCF in the presence of external bulk fields or, respectively, a nonzero total order parameter within the film. Our analytical results are supported by Monte Carlo simulations of the three-dimensional Ising model. We show that, in the canonical ensemble, i.e., when fixing the so-called total mass within the film, the CCF is typically repulsive instead of attractive as in the grand canonical ensemble. Based on the Landau-Ginzburg free energy, we furthermore obtain analytic expressions for the order parameter profiles and analyze the relation between the total mass in the film and the external bulk field.

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Christian M. Rohwer, Alessio Squarcini, Oleg Vasilyev, S. Dietrich, Markus Gross. 2019-06-11. Ensemble dependence of Critical Casimir Forces in Films with Dirichlet Boundary Conditions. https://doi.org/10.1103/physreve.99.062103

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