arXiv · 1908.03508
Many-body correlations from integral geometry
Abstract
In a recent letter we presented a framework for predicting the concentrations of many-particle local structures inside the bulk liquid as a route to assessing changes in the liquid approaching dynamical arrest. Central to this framework was the morphometric approach, a synthesis of integral geometry and liquid state theory, which has traditionally been derived from fundamental measure theory. We present the morphometric approach in a new context as a generalisation of scaled particle theory, and derive several morphometric theories for hard spheres of fundamental and practical interest. Our central result is a new theory which is particularly suited to the treatment of many-body correlation functions in the hard sphere liquid, which we demonstrate by numerical tests against simulation.
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Joshua F. Robinson, Francesco Turci, Roland Roth, C. Paddy Royall. 2019-08-09. Many-body correlations from integral geometry. https://doi.org/10.1103/physreve.100.062126
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