Effect of surface morphology on kinetic compensation effect

Nayeli Zuniga-Hansen; Leonardo E. Silbert; M. Mercedes Calbi

Home/Archive/arXiv

arXiv · 1909.05741

Effect of surface morphology on kinetic compensation effect

Nayeli Zuniga-Hansen·Leonardo E. Silbert·M. Mercedes Calbi

View original source ↗Read source document ↗Export metadata ↓

Abstract

As part of a systematic study on the kinetic compensation effect, we use kinetic Monte Carlo simulations to observe the effects of substrate topology on the transient variations in the Arrhenius parameters - effective activation energy $E_{a}$, and preexponential factor $\nu$ - during thermal desorption, with a particular focus on differences between ordered and disordered surfaces at a fixed global coordination number. The rates of desorption depend on surface configuration due to the inherent differences in the local environments of adsorbing sites in the two cases. While the compensation effect persists for the disordered substrate, the change in topology introduces an element that produces variations in $\nu$ that are independent of variations in $E_{a}$, which implies that the parameters cannot be fully characterized as functions of each other. We expect our results to provide a deeper insight into the microscopic events that originate compensation effects in our system of study but also in other fields where these effects have been reported.

Explore related subjects

cond-mat.stat-mech cond-mat.dis-nn physics.chem-ph

Keep this discovery

BibTeX RIS

Nayeli Zuniga-Hansen, Leonardo E. Silbert, M. Mercedes Calbi. 2019-09-12. Effect of surface morphology on kinetic compensation effect. https://arxiv.org/abs/1909.05741

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech↗

arXiv2026

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech↗

arXiv2026

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech↗