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arXiv · 2003.13366

Short time dynamics of tracer in ideal gas

Fumiaki Nakai·Yuichi Masubuchi·Takashi Uneyama
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Abstract

A small tagged particle immersed in a fluid exhibits the Brownian motion and diffuses at the long-time scale. Meanwhile, at the short-time scale, the dynamics of the tagged particle cannot be simply described by the usual generalized Langevin equation with the Gaussian noise, since the number of collisions between the tagged particle and fluid particles is rather small. At such a time scale, we should explicitly consider individual collision events between the tagged particle and the surrounding fluid particles. In this study, we analyzed the short-time dynamics of the tagged particle in an ideal gas, where we do not have static nor hydrodynamic correlations between fluid particles. We performed event-driven hard sphere simulations and show that the short-time dynamics of the tagged particle is correlated even under such an idealized situation. Namely, the velocity autocorrelation function becomes negative when the tagged particle is relatively light and the fluid density is relatively high. This result can be attributed to the dynamical correlation between collision events. To investigate the physical mechanism, which causes the dynamical correlation, we analyzed the correlation between successive collision events. We found that the tagged particle can collide with the same ideal gas particle several times, and such collisions cause the strong dynamical correlation for the velocity.

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Fumiaki Nakai, Yuichi Masubuchi, Takashi Uneyama. 2020-03-30. Short time dynamics of tracer in ideal gas. https://doi.org/10.1103/physreve.102.032104

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