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arXiv · 2004.12607

Linear versus nonlinear electro-optic effects in materials

Zhijun Jiang·Charles Paillard·Hongjun Xiang·L. Bellaiche
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Abstract

Two schemes are proposed to compute the nonlinear electro-optic (EO) tensor for the first time. In the first scheme, we compute the linear EO tensor of the structure under a finite electric field, while we compute the refractive index of the structure under a finite electric field in the second scheme. Such schemes are applied to Pb(Zr,Ti)O$_{3}$ and BaTiO$_{3}$ ferroelectric oxides. It is found to reproduce a recently observed feature, namely why Pb(Zr$_{0.52}$Ti$_{0.48}$)O$_{3}$ adopts a mostly linear EO response while BaTiO$_{3}$ exhibits a strongly nonlinear conversion between electric and optical properties. Furthermore, the atomistic insight provided by the proposed ab-initio scheme reveals the origin of such qualitatively different responses, in terms of the field-induced behavior of the frequencies of some phonon modes and of some force constants.

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Zhijun Jiang, Charles Paillard, Hongjun Xiang, L. Bellaiche. 2020-04-27. Linear versus nonlinear electro-optic effects in materials. https://doi.org/10.1103/physrevlett.125.017401

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