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arXiv · 2008.06087

A latent heat method to detect melting and freezing of metals at megabar pressures

Zachary M. Geballe·Nicholas Holtgrewe·Amol Karandikar·Eran Greenberg·Vitali B. Prakapenka·Alexander F. Goncharov
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Abstract

The high-pressure melting curves of metals provide simple and useful tests for theories of melting, as well as important constraints for the modeling of planetary interiors. Here, we present an experimental technique that reveals the latent heat of fusion of a metal sample compressed inside a diamond anvil cell. The technique combines microsecond-timescale pulsed electrical heating with an internally-heated diamond anvil cell for the first time. Further, we use the technique to measure the melting curve of platinum to the highest pressure measured to date. Melting temperature increases from $\sim 3000$ K at 34 GPa to $\sim 4500$ K at 107 GPa, thermodynamic conditions that are between the steep and shallow experimental melting curves reported previously. The melting curve is a linear function of compression over the 0 to 20% range of compression studied here, allowing a good fit to the Kraut-Kennedy empirical model with fit parameter $C=6.0$.

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Zachary M. Geballe, Nicholas Holtgrewe, Amol Karandikar, Eran Greenberg, Vitali B. Prakapenka, Alexander F. Goncharov. 2020-08-13. A latent heat method to detect melting and freezing of metals at megabar pressures. https://doi.org/10.1103/physrevmaterials.5.033803

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