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arXiv · 2011.03222

Multi-chain slip-spring simulations with various slip-spring densities

Yuichi Masubuchi·Yuya Doi·Takashi Uneyama
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Abstract

Although it has been established that the multi-chain slip-spring (MCSS) model can reproduce entangled polymer dynamics, the effects of model parameters have not been fully elucidated yet. In this study, we systematically investigated the effects of slip-spring density. For the diffusion and the linear viscoelasticity, the simulation results exhibited universality. Namely, the results from the simulations with various slip-spring densities can be superposed with each other by the conversion factors for the bead number per chain, unit of length, unit of time, and modulus. The diffusion and the viscoelasticity were in good agreement with the literature data for the standard bead-spring simulations, including the molecular weight dependence. The universality among the MCSS simulations with various slip-spring density also held under mild shear if the slip-spring density was not significantly high. The results imply that the level of coarse-graining for the MCSS model can be arbitrarily chosen as in the Rouse model.

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Yuichi Masubuchi, Yuya Doi, Takashi Uneyama. 2020-11-06. Multi-chain slip-spring simulations with various slip-spring densities. https://arxiv.org/abs/2011.03222

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