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arXiv · 2109.10185

The rovibrational Aharonov-Bohm effect

Jonathan I. Rawlinson·Csaba Fábri·Attila G. Császár
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Abstract

Another manifestation of the Aharonov-Bohm effect is introduced to chemistry, in fact to nuclear dynamics and high-resolution molecular spectroscopy. As demonstrated, the overall rotation of a symmetric-top molecule influences the dynamics of an internal vibrational motion in a way that is analogous to the presence of a solenoid carrying magnetic flux. To a good approximation, the low-energy rovibrational energy-level structure of the quasistructural molecular ion H5+ can be understood entirely in terms of this effect.

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Jonathan I. Rawlinson, Csaba Fábri, Attila G. Császár. 2021-09-21. The rovibrational Aharonov-Bohm effect. https://doi.org/10.1039/d1cp03358a

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