Searcharxiv⌕ Search
Home/Archive/arXiv

arXiv · 2111.02942

An investigation of factors affecting high-precision Sr isotope analyses (87Sr/86Sr and {\delta}88/86Sr) by MC-ICP-MS

Jiuyuan Wang·Dan Asael·Noah J. Planavsky·Lidya G. Tarhan
View original source ↗Read source document ↗Export metadata ↓

Abstract

The abundance and fractionation of the stable strontium (Sr) isotope system are being increasingly utilized to move forward our understanding in geological and cosmological processes. Two analytical techniques are commonly used to measure stable Sr isotopes: 1) double-spike thermal ionization mass spectrometry (DS-TIMS) and 2) Zr-doped sample-standard bracketing multi-collector inductively coupled plasma mass spectrometry (Zr-doped SSB via MC-ICP-MS). Relative to DS-TIMS, Zr-doped SSB via MC-ICP-MS allows simultaneous determinations of both 87Sr/86Sr and 88Sr/86Sr ratios, increasing measurement efficiency and sample throughput. However, this technique is currently associated with greater uncertainties in measurement precision and accuracy. In this study, we evaluated potential factors that can affect the quality of Sr isotope measurements during Zr-doped SSB. Our tests show that incomplete Sr recovery during chromatographic separation, mismatches of Sr and Zr concentrations and acid molarity between sample and bracketing standard, and cation contamination could all affect the precision and accuracy of Sr isotope measurements. We present evidence that, with updated preparation procedures and diligent concentration checks, a long-term reproducibility (2{\sigma}SD: 87Sr/86Sr = +/-0.000015 and {\delta}88/86Sr = +/-0.03 permil) comparable to that of DS-TIMS is achievable when using the Zr-doped SSB method via MC-ICP-MC.

Explore related subjects

physics.geo-phastro-ph.IM

Keep this discovery

BibTeXRIS

Jiuyuan Wang, Dan Asael, Noah J. Planavsky, Lidya G. Tarhan. 2021-11-04. An investigation of factors affecting high-precision Sr isotope analyses (87Sr/86Sr and {\delta}88/86Sr) by MC-ICP-MS. https://doi.org/10.1016/j.chemgeo.2023.121365

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Holistic law of aftershocks

The paper is devoted to the phenomenological theory of aftershocks occurring in the source of a tectonic earthquake following the main shock. The theory was developed by the author jointly with A.D. Zavyalov and O.D. Zotov during the course of a long-term study of aftershocks. The theory is based on the concepts of source deactivation and the source's proper time. The holistic law governing the decay of aftershock activity over proper time follows from the theory. The damping decrement is equal to the source deactivation coefficient. The main focus of this paper is the analysis of the logical structure of the theory. The paper also contains a brief description of the experimental results obtained using the theory. Keywords: earthquake source, aftershocks, Omori's law, Utsu's law, deactivation coefficient, proper time, underground clock, foreshock convergence, aftershock divergence.

physics.geo-ph↗
arXiv2026

Bayesian deep learning integration of geophysical and drilling data for 3D prediction of copper mineralization and drill targeting: a case study from the Kogodai prospect, Rudny Altai

Exploration drill targeting in structurally complex terranes is hindered by sparse sampling, heterogeneous datasets, and the ambiguity of geophysical inversions. Here, we present an uncertainty-aware 3D workflow for the acceleration of time-to-discovery in brownfield explorations and apply it to the Kogodai prospect in the Rudny Altai metallogenic province. We jointly analyse existing drilling and geophysical data in a comprehensive approach, revealing hidden patterns in already available data. Drillholes and trenches were desurveyed to a common 3D reference frame, and assays were composited to a consistent spatial support to facilitate joint modelling with geophysical inputs. We develop Bayesian deep-learning models to predict 3D fields of Cu grade together with chargeability and apparent resistivity while quantifying epistemic uncertainty via Monte Carlo sampling. The original contribution of this work is to treat the problem not as pointwise regression between co-located observations, but as joint learning of spatially continuous 3D fields from sparse, heterogeneous exploration evidence. The resulting 3D predictions delineate a principal mineralized trend and several localized candidate zones that coincide with elevated induced polarization (IP) responses, while uncertainty mapping highlights where predictions are robust versus where additional drilling would be most informative. The continuous Cu-grade field can also be thresholded to produce binary prospectivity maps, allowing the sensitivity of target delineation to the chosen cutoff to be evaluated. The outputs are intended for qualitative interpretation and risk-aware drill targeting rather than resource estimation, and we discuss key limitations arising from incomplete provenance metadata for geophysical products and heterogeneity of historical sampling.

physics.geo-ph↗
arXiv2026

PyelogP: Automated Energy-Based Determination of Preconsolidation Pressure in Clay Deposits

Estimating the preconsolidation pressure ($\sigma'_p$) from one-dimensional consolidation (oedometer) tests is critical in geotechnical engineering for settlement analysis. Traditional graphical methods, such as the Casagrande procedure, may introduce uncertainties, particularly when interpreting rounded $e$-log($P$) curves typical of disturbed specimens of soft clays and silt deposits. This paper introduces PyelogP, an open-source Python library designed to calculate $\sigma'_p$ using the strain-energy method proposed by Becker et al. (1987) as an automated and reproducible alternative. The algorithm combines natural cubic spline interpolation, knee-point detection via the Kneedle algorithm, and split-point linear regression within the work-pressure space. Physically informed thresholds, including overconsolidation ratio limits and second-derivative maxima (${d^2 e}/{d(\log \sigma')^2}$), are incorporated to establish pre-yield and post-yield fitting boundaries. The performance of PyelogP is evaluated against a suite of 22 experimental consolidation datasets covering various clay deposits, including Saint-Alban clay and San Francisco Old Bay Clay. The results demonstrate strong agreement with the published values ($R^2$ = 0.912, RMSE = 0.374, MBE = -0.080), while the $O(N^2)$ algorithm requires only a few milliseconds per curve for typical oedometer datasets and less than 150 milliseconds for the largest datasets.

physics.geo-ph↗