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arXiv · 2202.07083

Role of lithium intercalation in fluorine-doped tin oxide thin films: Ab-initio calculations and experiment

Israel Perez·Victor Sosa·Fidel Gamboa·Jose Luis Enriquez-Carrejo·Juan Carlos Mixteco Sanchez
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Abstract

Using a combination of experimental techniques and density functional theory (DFT) calculations, the influence of lithium insertion on the electronic and electrochemical properties of fluourine-doped SnO$_2$ (FTO) is assessed. For this purpose, we investigate the electrochromic behavior of commercial FTO electrode embedded in a solution of lithium perclorate (LiClO$_4$). The electrochromic properties are evaluated by UV-VIS spectroscopy, cyclic voltammetry, and chronoamperometry. These tests show that FTO exhibits electrochromism with a respectable coloration efficiency ($\eta=47.9$ cm$^2$/C @ 637 nm). DFT study indicates that lithium remains ionized in the lattice, raising the Fermi level about 0.7 eV deep into the conduction band. X-ray photoelectron spectroscopy (XPS) is used to study chemical bonding and oxidation states. XPS analysis of the Sn 3d core levels reveals that lithium insertion in FTO induces a shift of 350 meV in the Sn 3d states suggesting that lithium is incorporated into the SnO$_2$ lattice.

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Israel Perez, Victor Sosa, Fidel Gamboa, Jose Luis Enriquez-Carrejo, Juan Carlos Mixteco Sanchez. 2022-02-14. Role of lithium intercalation in fluorine-doped tin oxide thin films: Ab-initio calculations and experiment. https://doi.org/10.1063/5.0085531

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