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arXiv · 2204.03811

Observation of Mesoscopic Clathrate Structures in Ethanol-Water Mixtures

Wei-Hao Hsu·Tzu-Chieh Yen·Chien-Chun Chen·Chih-Wen Yang·Chung-Kai Fang·Ing-Shouh Hwang
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Abstract

Water-alcohol mixtures exhibit many abnormal physicochemical properties, the origins of which remain controversial. Here we use transmission electron microscopy (TEM), nanoparticle tracking analysis (NTA), and atomic force microscopy (AFM) to study ethanol-water mixtures. TEM reveals mesoscopic clathrate structures with water molecules forming a crystalline matrix hosting a high density of tiny cells. The presence of these mesoscopic clathrate structures is further supported by a refractive index of 1.27+-0.02 at 405 nm measured via NTA and the hydrophilic nature of the mesoscopic structures implied by AFM observations, explaining many long-standing puzzles related to water-alcohol mixtures.

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Wei-Hao Hsu, Tzu-Chieh Yen, Chien-Chun Chen, Chih-Wen Yang, Chung-Kai Fang, Ing-Shouh Hwang. 2022-04-08. Observation of Mesoscopic Clathrate Structures in Ethanol-Water Mixtures. https://arxiv.org/abs/2204.03811

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