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arXiv · 2205.06413

Correlated driving-and-dissipation equation for non-Condon spectroscopy with the Herzberg-Teller vibronic coupling

Jie Fang·Zi-Hao Chen·Yao Wang·Rui-Xue Xu·YiJing Yan
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Abstract

Correlated driving-and-dissipation equation (CODDE) is an optimized complete second-order quantum dissipation approach, which is originally concerned with the reduced system dynamics only. However, one can actually extract the hybridized bath dynamics from CODDE with the aid of dissipaton-equation-of-motion theory, a statistical quasi-particle quantum dissipation formalism. Treated as an one{dissipaton theory, CODDE is successfully extended to deal with the Herzberg-Teller vibronic couplings in dipole-field interactions. Demonstrations will be carried out on the non-Condon spectroscopies of a model dimer system.

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Jie Fang, Zi-Hao Chen, Yao Wang, Rui-Xue Xu, YiJing Yan. 2022-05-13. Correlated driving-and-dissipation equation for non-Condon spectroscopy with the Herzberg-Teller vibronic coupling. https://doi.org/10.1002/jccs.202200222

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