Equilibria in Electrochemistry and Maximal Rates of Reaction

Tristram de Piro

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arXiv · 2209.12363

Equilibria in Electrochemistry and Maximal Rates of Reaction

Tristram de Piro

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Abstract

We consider Gibbs' definition of chemical equilibrium and connect it with dynamic equilibrium, in terms of no substance formed. We determine the activity coefficient as a function of temperature and pressure, in reactions with or without interaction of a solvent, incorporating the error terms from Raoult's Law and Henry's Law, if necessary. We compute the maximal reaction paths and apply the results to electrochemistry, using the Nernst equation.

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Tristram de Piro. 2022-09-26. Equilibria in Electrochemistry and Maximal Rates of Reaction. https://arxiv.org/abs/2209.12363

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