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arXiv · 2301.08458

Real-time microscopic view of the relaxation of a glass

Abstract

The understanding of glassy dynamics above the devitrification temperature of a glass remains poorly understood. Here, we use real-time AFM imaging to build a spatio-temporal map of the relaxation dynamics of a highly stable glass into its supercooled liquid. This new methodology enables a direct visualization of the progression of the liquid phase and clarifies and quantifies the presence of localized fast mobility regions separated by giant length scales. Our data permit to establish a clear correlation between dynamic length and time scales in glasses. This approach may also be applicable to unveil the microscopic structure and dynamics of other glass forming systems with much shorter length and time scales, including liquid-cooled glasses.

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Marta Ruiz-Ruiz, Ana Vila-Costa, Tapas Bar, Cristian Rodríguez-Tinoco, Marta Gonzalez-Silveira, Jose Antonio Plaza, Jorge Alcalá, Jordi Fraxedas, Javier Rodriguez-Viejo. 2023-01-20. Real-time microscopic view of the relaxation of a glass. https://doi.org/10.1038/s41567-023-02125-0

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