arXiv subjects

Tapas Bar

Publications and source records attributed to Tapas Bar.

9 recordsLinked to original sources

arXiv2026

Fluctuation-Controlled Asymmetric Kinetics in Metal-Insulator Transitions

We report asymmetric kinetics in thermally driven metal-insulator transitions (MITs) in 1T-TaS$_2$. Using combined transport, calorimetric, and Raman measurements, we show that the transition proceeds via burst-like avalanches during cooling, while remaining continuous during heating. Although bulk transport is masked by percolative conduction, local probes and thermal measurements reveal intrinsic asymmetry in the transformation pathways. Using controlled nonequilibrium thermal perturbations generated by pulsed Joule heating, we demonstrate that the phase-ordering dynamics remains strongly athermal during cooling, whereas during heating fluctuations progressively overcome nucleation barriers, leading to a smooth transformation. The distinct responses to thermal perturbations indicate different degrees of athermality of the two hysteresis branches, which govern the transformation pathways and give rise to the observed kinetic asymmetry. These results establish a general framework in which the degree of athermality controls pathway selection in first-order phase transitions.

cond-mat.stat-mech↗

arXiv2026

Domain-induced control of latent heat in freestanding BaTiO$_3$ membranes

Thin ferroelectric BaTiO$_3$ films often exhibit continuous transitions instead of the first-order behavior of bulk crystals, a discrepancy usually attributed to epitaxial strain or dimensionality. Using quasi-adiabatic nanocalorimetry on freestanding BaTiO$_3$ membranes-free of clamping and substrate heat sinking-we show that domain morphology, not thickness or boundary conditions, controls the transition order. Thick membranes with large, monodomain-like regions display clear latent heat, whereas thinner membranes with dense 180$^{\circ}$ domain patterns show a continuous transition despite undergoing the same tetragonal-cubic structural change confirmed by x-ray diffraction. Piezoresponse force microscopy links this behavior to domain-size evolution, and a Ginzburg-Landau analysis demonstrates how reduced domain size lowers the free-energy barrier, rounding a nominally first-order instability. These results identify domain morphology as the key determinant of ferroelectric transition order in oxide membranes and establish design guidelines for enhancing caloric effects through domain engineering.

cond-mat.mtrl-sci↗

arXiv2025

Disorder-aided Early Warning Signals: Predicting Catastrophic Shifts in Athermal Systems

The early prediction of tipping points, distinguished by sudden and catastrophic shifts from stable states, poses a challenging task that would enable us to assess the impending threat across natural and engineered systems. This threat becomes particularly acute in low-fluctuation environments, where tipping occurs through saddle-node bifurcation without prior warning in noise dynamics. In this study, we investigate the tipping point dynamics of avalanche catastrophes in low-fluctuation domain, employing model system like the zero temperature random field Ising model and thermally deposited cobalt films. As the system approaches the tipping point, avalanche activity reveals pronounced critical behaviour, including critical slowing down, variance enhancement, and a growing spatial correlation length--hallmarks that may serve as early warning signals of impending collapse. Crucially, we demonstrate that increasing disorder in the system reduces its vulnerability to catastrophic failure. In highly disorder regimes, these early warning signals emerge well before the transition, thereby providing a large margin for anticipation and mitigation. This key finding suggests a protective role of disorder offering a novel perspective on resilience in complex systems. Our results not only deepen the understanding of tipping phenomena in disorder materials but also have broader implications for forecasting regime shift in diverse real-world systems.

cond-mat.stat-mech↗

arXiv2023

Real-time microscopic view of the relaxation of a glass

The understanding of glassy dynamics above the devitrification temperature of a glass remains poorly understood. Here, we use real-time AFM imaging to build a spatio-temporal map of the relaxation dynamics of a highly stable glass into its supercooled liquid. This new methodology enables a direct visualization of the progression of the liquid phase and clarifies and quantifies the presence of localized fast mobility regions separated by giant length scales. Our data permit to establish a clear correlation between dynamic length and time scales in glasses. This approach may also be applicable to unveil the microscopic structure and dynamics of other glass forming systems with much shorter length and time scales, including liquid-cooled glasses.

physics.app-ph↗

arXiv2023

Critical Slowing Down at the Abrupt Mott Transition: When the First-Order Phase Transition Becomes Zeroth-Order and Looks Like Second-Order

We report that the thermally-induced Mott transition in vanadium sesquioxide shows critical-slowing-down and enhanced variance ('critical opalescence') of the order parameter fluctuations measured through low-frequency resistance-noise spectroscopy. Coupled with the observed increase of also the phase-ordering time, these features suggest that the strong abrupt transition is controlled by a critical-like singularity in the hysteretic metastable phase. The singularity is identified with the spinodal point and is a likely consequence of the strain-induced long-range interaction.

cond-mat.stat-mech↗

arXiv2022

Finite-dimensional signature of spinodal instability in an athermal hysteretic transition

We study the off-equilibrium critical phenomena across a hysteretic first-order transition in disordered athermal systems. The study focuses on the zero temperature random field Ising model (ZTRFIM) above the critical disorder for spatial dimensions $d=2,3,$ and $4$. We use Monte Carlo simulations to show that disorder suppresses critical slowing down in phase ordering time for finite-dimensional systems. The dynamic hysteresis scaling, the measure of explicit finite-time scaling, is used to subsequently quantify the critical slowing down. The scaling exponents in all dimensions increase with disorder strength and finally reach a stable value where the transformation is no longer critical. The associated critical behavior in the mean-field limit is very different, where the exponent values for various disorders in all dimensions are similar. The non-mean-field exponents asymptotically approach the mean-field value ($\Upsilon \approx 2/3$) with increase in dimensions. The results suggest that the critical features in the hysteretic metastable phase are controlled by inherent mean-field spinodal instability that gets blurred by disorder in low-dimension athermal systems.

cond-mat.stat-mech↗

arXiv2021

Absolute calibration of the latent heat of transition using differential thermal analysis

We describe a simple and accurate differential thermal analysis set up to measure the latent heat of solid state materials undergoing abrupt phase transitions in the temperature range from 77 K to above room temperature. We report a numerical technique for the absolute calibration of the latent heat of the transition, without the need of a reference sample. The technique is applied to three different samples -- vanadium sesquioxide undergoing the Mott transition, bismuth barium ruthenate undergoing a magnetoelastic transition, and an intermetallic Heusler compound. In each case, the inferred latent heat value agrees with the literature value to within its error margins. To further demonstrate the importance of absolute calibration, we show that the changes in the latent heat of the Mott transition in vanadium sesquioxide (V$_2$O$_3$) stays constant to within 2% even as the depth of supersaturation changes by about 10 K, in non-equilibrium dynamic hysteresis measurements. We also apply this technique for the measurement of the temperature-dependent specific heat.

cond-mat.stat-mech↗

arXiv2021

Suppression of spinodal instability by disorder in an athermal system

We observed asymmetric critical slowing down and asymmetric dynamical scaling exponent in the superheating and supercooling kinetic processes during the thermally-induced metal-insulator transition of MnNiSn based heusler alloy. During the transition to the insulator phase, the critical-like features get enhanced compared to the transition back to the metal phase. These experimental findings suggest that the metastable phase in the cooling branch of hysteresis has approached close to the spinodal instability. On the other hand, the extended disorder, generated over and above the intrinsic crystal defects during heating, triggers the excess heterogeneous nucleation before reaching the spinodal point. Zero temperature random field Ising model (ZTRFIM) simulation, inscribed for the athermal martensitic transitions, support the argument that the disorder smears the spinodal instabilities as the correlation length is bounded by the average distance between the disorder points.

cond-mat.stat-mech↗

arXiv2018

Kinetic Spinodal Instabilities in the Mott Transition in V2O3: Evidence from Hysteresis Scaling and Dissipative Phase Ordering

We present the first systematic observation of scaling of thermal hysteresis with the temperature scanning rate around an abrupt thermodynamic transition in correlated electron systems. We show that the depth of supercooling and superheating in vanadium sesquioxide (V2O3) shifts with the temperature quench rates. The dynamic scaling exponent is close to the mean field prediction of 2/3. These observations, combined with the purely dissipative continuous ordering seen in "quench-and-hold" experiments, indicate departures from classical nucleation theory toward a barrier-free phase ordering associated with critical dynamics. Observation of critical-like features and scaling in a thermally induced abrupt phase transition suggests that the presence of a spinodal-like instability is not just an artifact of the mean field theories but can also exist in the transformation kinetics of real systems, surviving fluctuations.

cond-mat.stat-mech↗