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arXiv · 2302.10492

Conversion of stable crystals to metastable crystals in a solution by periodic change of temperature

Hiroyasu Katsuno·Makio Uwaha
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Abstract

Using a Becker-D\"oring type model including cluster incorporation, we study the possibility of conversion of stable crystals to metastable crystals in a solution by a periodic change of temperature. At low temperature, both stable and metastable crystals grow by coalescence with abundant clusters. At high temperature, a large amount of small clusters produced by the dissolution of crystals inhibits the dissolution of crystals, and the imbalance in the amount of crystals increases. By repeating this process, the periodic temperature change can convert stable crystals into metastable crystals.

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Hiroyasu Katsuno, Makio Uwaha. 2023-02-21. Conversion of stable crystals to metastable crystals in a solution by periodic change of temperature. https://doi.org/10.1103/physreve.107.044114

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