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arXiv · 2404.01286

Beyond Linear Response: Equivalence between Thermodynamic Geometry and Optimal Transport

Adrianne Zhong·Michael R. DeWeese
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Abstract

A fundamental result of thermodynamic geometry is that the optimal, minimal-work protocol that drives a nonequilibrium system between two thermodynamic states in the slow-driving limit is given by a geodesic of the friction tensor, a Riemannian metric defined on control space. For overdamped dynamics in arbitrary dimensions, we demonstrate that thermodynamic geometry is equivalent to $L^2$ optimal transport geometry defined on the space of equilibrium distributions corresponding to the control parameters. We show that obtaining optimal protocols past the slow-driving or linear response regime is computationally tractable as the sum of a friction tensor geodesic and a counterdiabatic term related to the Fisher information metric. These geodesic-counterdiabatic optimal protocols are exact for parameteric harmonic potentials, reproduce the surprising non-monotonic behavior recently discovered in linearly-biased double well optimal protocols, and explain the ubiquitous discontinuous jumps observed at the beginning and end times.

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Adrianne Zhong, Michael R. DeWeese. 2024-04-01. Beyond Linear Response: Equivalence between Thermodynamic Geometry and Optimal Transport. https://doi.org/10.1103/physrevlett.133.057102

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