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arXiv · 2504.15169

Improving efficiency and stability for perovskite solar cell with diethylene glycol dimethacrylate modification

Xiaodan Wei·Shuyuan Zhang·Boyang Ma·Zehua Feng·chunhan Yu·Linyuan Peng·Zijian Hua·Jie Xu
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Abstract

The humidity resistance is the key challenges that hinder the commercial application of perovskite solar cells (PSCs). Herein, we propose an ultra-thin acrylate polymer (diethylene glycol dimethacrylate, DGDMA) into perovskite films to investigate the influence of polymerized networks on stability. The monomer molecules containing acrylate and carbonyl groups were selected, and the effects of the polymerized were quantified with different concentration. The experimental results show that, when the concentration of DGDMA is 1 mg/ml, the PCE increases from 18.06% to 21.82%, which is optimum. The monomer molecules with carbonyl groups polymerize, they can chelate with uncoordinated Pb2+ in perovskite films to improve the film quality, reduce the surface defect density to decrease non-radiative recombination, and also significantly enhance the humidity stability of PSCs.

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Xiaodan Wei, Shuyuan Zhang, Boyang Ma, Zehua Feng, chunhan Yu, Linyuan Peng, Zijian Hua, Jie Xu. 2025-04-21. Improving efficiency and stability for perovskite solar cell with diethylene glycol dimethacrylate modification. https://arxiv.org/abs/2504.15169

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