Efficient $GW$ band structure calculations using Gaussian basis functions and application to atomically thin transition-metal dichalcogenides

Abstract

We present a $GW$ space-time algorithm for periodic systems in a Gaussian basis including spin-orbit coupling. We employ lattice summation to compute the irreducible density response and the self-energy, while we employ $k$-point sampling for computing the screened Coulomb interaction. Our algorithm enables accurate and computationally efficient quasiparticle band structure calculations for atomically thin transition-metal dichalcogenides. For monolayer MoS$_\text{2}$, MoSe$_\text{2}$, WS$_\text{2}$, and WSe$_\text{2}$, computed $GW$ band gaps agree on average within 50 meV with plane-wave-based reference calculations. $G_0W_0$ band structures are obtained in less than two days on a laptop (Intel i5, 192 GB RAM) or in less than 30 minutes using 1024 cores. Overall, our work provides an efficient and scalable framework for $GW$ calculations on atomically thin materials.