Oxygen incorporation in YBa$_2$Cu$_3$O$_{7-\delta}$ thin films: surface activation and degradation

Abstract

The oxygen off-stoichiometry plays a pivotal role for the physical properties of superconducting oxides. Yet, there is a lack of knowledge on the fundamental processes of oxygen incorporation and correlated phenomena during oxygen post annealing treatments. Here, we deployed electrical probes ($\rho(T)$ and electrical conductivity relaxation (ECR) measurements) to gain a better understanding of the kinetics of the oxygen reduction reaction (ORR) in epitaxial YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) thin films. We identified a new indicator for the onset temperature of oxygen incorporation and report for the first time drastic kinetic deactivation in bare YBCO. We demonstrate that surface decoration using silver micro islands both catalytically activates oxygen incorporation and bypasses surface degradation processes. Our results suggest that the ORR in the studied YBCO samples is limited by a surface reaction. Additionally, weak XRD signatures of the formation of extended bulk defects were identified, which have to be considered in the designing of an optimal oxygenation treatment to obtain best performing superconducting YBCO.