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arXiv · 2601.12477

A non-equilibrium strategy for the general synthesis of single-atom catalysts

Yue Li·Yang Xu·Yunbiao Zhao·Mingwei Cui·Xiner Chen·Liu Qian·Jin Zhang·Xueting Feng·Ziqiang Zhao
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Abstract

Single-atom catalysts (SACs) maximize atom efficiency and exhibit unique electronic structures, yet realizing precise and scalable atomic dispersion remains a key challenge. Here, we report a non-equilibrium strategy for the scalable synthesis of SACs via ion implantation, enabling precise stabilization of metal atoms on diverse supports. Using an industrial-grade ion source, wafer-scale ion implantation with milliampere-level beam currents enables high-throughput fabrication of SACs, while the synergistic energy-mass effects stabilize isolated metal atoms in situ. A library of 36 SACs was constructed, and the resulting Pt/MoS2 exhibits outstanding hydrogen evolution performance with an overpotential of only 26 mV at 10 mA cm-2 and exceptional long-term stability, surpassing commercial Pt/C. This work demonstrates ion implantation as a versatile platform bridging fundamental SACs design and scalable manufacturing, providing new opportunities for high-performance catalysts in energy conversion applications.

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Yue Li, Yang Xu, Yunbiao Zhao, Mingwei Cui, Xiner Chen, Liu Qian, Jin Zhang, Xueting Feng, Ziqiang Zhao. 2026-01-18. A non-equilibrium strategy for the general synthesis of single-atom catalysts. https://arxiv.org/abs/2601.12477

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