arXiv subjects

Ziqiang Zhao

Publications and source records attributed to Ziqiang Zhao.

9 recordsLinked to original sources

arXiv2026

Subsurface Vacancy Engineering Enables Atomically Clean and Oxidation-Resistant Copper Interfaces for Anode-Free Lithium Metal Batteries

Interfaces govern reaction pathways and stability in electrochemical systems, yet creating clean, well-defined metal interfaces at scale remains challenging. In anode-free lithium metal batteries (AFLMBs), the current-collector interface is decisive for lithium nucleation and solid electrolyte interphase (SEI) formation, and ideally should support efficient charge transport, uniform reaction distribution, and long-term chemical and structural stability. Here we report an ion-implantation strategy that produces an atomically clean and oxidation-resistant copper interface. Implanting copper ions into commercial foils removes the native oxide while generating subsurface vacancy clusters directly beneath the surface -- an atomic-scale modification that does not increase the collector thickness but fundamentally alters interfacial chemistry. Experiments and multiscale simulations reveal that these vacancies act as strong oxygen traps, preventing reoxidation, enhancing interfacial conductivity, and guiding the formation of an ultrathin, Li2O-enriched SEI that promotes uniform lithium deposition and suppresses parasitic reactions. Applied in AFLMBs, the engineered current collectors deliver long-term stability with a Coulombic efficiency of 98.8% over 600 cycles under lean-electrolyte conditions. These findings demonstrate atomic-scale interface control of copper current collectors as a route toward stable and practical lithium metal batteries.

cond-mat.mtrl-sci↗

arXiv2026

InSpatio-WorldFM: An Open-Source Real-Time Generative Frame Model

We present InSpatio-WorldFM, an open-source real-time frame model for spatial intelligence. Unlike video-based world models that rely on sequential frame generation and incur substantial latency due to window-level processing, InSpatio-WorldFM adopts a frame-based paradigm that generates each frame independently, enabling low-latency real-time spatial inference. By enforcing multi-view spatial consistency through explicit 3D anchors and implicit spatial memory, the model preserves global scene geometry while maintaining fine-grained visual details across viewpoint changes. We further introduce a progressive three-stage training pipeline that transforms a pretrained image diffusion model into a controllable frame model and finally into a real-time generator through few-step distillation. Experimental results show that InSpatio-WorldFM achieves strong multi-view consistency while supporting interactive exploration on consumer-grade GPUs, providing an efficient alternative to traditional video-based world models for real-time world simulation.

cs.CV↗

arXiv2026

INSPATIO-WORLD: A Real-Time 4D World Simulator via Spatiotemporal Autoregressive Modeling

Building world models with spatial consistency and real-time interactivity remains a fundamental challenge in computer vision. Current video generation paradigms often struggle with a lack of spatial persistence and insufficient visual realism, making it difficult to support seamless navigation in complex environments. To address these challenges, we propose INSPATIO-WORLD, a novel real-time framework capable of recovering and generating high-fidelity, dynamic interactive scenes from a single reference video. At the core of our approach is a Spatiotemporal Autoregressive (STAR) architecture, which enables consistent and controllable scene evolution through two tightly coupled components: Implicit Spatiotemporal Cache aggregates reference and historical observations into a latent world representation, ensuring global consistency during long-horizon navigation; Explicit Spatial Constraint Module enforces geometric structure and translates user interactions into precise and physically plausible camera trajectories. Furthermore, we introduce Joint Distribution Matching Distillation (JDMD). By using real-world data distributions as a regularizing guide, JDMD effectively overcomes the fidelity degradation typically caused by over-reliance on synthetic data. Extensive experiments demonstrate that INSPATIO-WORLD significantly outperforms existing state-of-the-art (SOTA) models in spatial consistency and interaction precision, ranking first among real-time interactive methods on the WorldScore-Dynamic benchmark, and establishing a practical pipeline for navigating 4D environments reconstructed from monocular videos.

cs.CV↗

arXiv2026

A non-equilibrium strategy for the general synthesis of single-atom catalysts

Single-atom catalysts (SACs) maximize atom efficiency and exhibit unique electronic structures, yet realizing precise and scalable atomic dispersion remains a key challenge. Here, we report a non-equilibrium strategy for the scalable synthesis of SACs via ion implantation, enabling precise stabilization of metal atoms on diverse supports. Using an industrial-grade ion source, wafer-scale ion implantation with milliampere-level beam currents enables high-throughput fabrication of SACs, while the synergistic energy-mass effects stabilize isolated metal atoms in situ. A library of 36 SACs was constructed, and the resulting Pt/MoS2 exhibits outstanding hydrogen evolution performance with an overpotential of only 26 mV at 10 mA cm-2 and exceptional long-term stability, surpassing commercial Pt/C. This work demonstrates ion implantation as a versatile platform bridging fundamental SACs design and scalable manufacturing, providing new opportunities for high-performance catalysts in energy conversion applications.

cond-mat.mtrl-sci↗

arXiv2024

Calibrated absolute optical contrast for high-throughput characterization of horizontally aligned carbon nanotube arrays

Horizontally aligned carbon nanotube (HACNT) arrays hold significant potential for various applications in nanoelectronics and material science. However, their high-throughput characterization remains challenging due to the lack of methods with both high efficiency and high accuracy. Here, we present a novel technique, Calibrated Absolute Optical Contrast (CAOC), achieved through the implementation of differential principles to filter out stray signals and high-resolution calibration to endow optical contrast with physical significance. CAOC offers major advantages over previous characterization techniques, providing consistent and reliable measurements of HACNT array density with high throughput and non-destructive assessment. To validate its utility, we demonstrate wafer-scale uniformity assessment by rapid density mapping. This technique not only facilitates the practical evaluation of HACNT arrays but also provides insights into balancing high throughput and high resolution in nanomaterial characterization.

physics.app-ph↗

arXiv2024

Transforming the Synthesis of Carbon Nanotubes with Machine Learning Models and Automation

Carbon-based nanomaterials (CBNs) are showing significant potential in various fields, such as electronics, energy, and mechanics. However, their practical applications face synthesis challenges stemming from the complexities of structural control, large-area uniformity, and high yield. Current research methodologies fall short in addressing the multi-variable, coupled interactions inherent to CBNs production. Machine learning methods excel at navigating such complexities. Their integration with automated synthesis platforms has demonstrated remarkable potential in accelerating chemical synthesis research, but remains underexplored in the nanomaterial domain. Here we introduce Carbon Copilot (CARCO), an artificial intelligence (AI)-driven platform that integrates transformer-based language models tailored for carbon materials, robotic chemical vapor deposition (CVD), and data-driven machine learning models, empowering accelerated research of CBNs synthesis. Employing CARCO, we demonstrate innovative catalyst discovery by predicting a superior Titanium-Platinum bimetallic catalyst for high-density horizontally aligned carbon nanotube (HACNT) array synthesis, validated through over 500 experiments. Furthermore, with the assistance of millions of virtual experiments, we achieved an unprecedented 56.25% precision in synthesizing HACNT arrays with predetermined densities in the real world. All were accomplished within just 43 days. This work not only advances the field of HACNT arrays but also exemplifies the integration of AI with human expertise to overcome the limitations of traditional experimental approaches, marking a paradigm shift in nanomaterials research and paving the way for broader applications.

physics.app-ph↗

arXiv2022

Multifaceted Improvements for Conversational Open-Domain Question Answering

Open-domain question answering (OpenQA) is an important branch of textual QA which discovers answers for the given questions based on a large number of unstructured documents. Effectively mining correct answers from the open-domain sources still has a fair way to go. Existing OpenQA systems might suffer from the issues of question complexity and ambiguity, as well as insufficient background knowledge. Recently, conversational OpenQA is proposed to address these issues with the abundant contextual information in the conversation. Promising as it might be, there exist several fundamental limitations including the inaccurate question understanding, the coarse ranking for passage selection, and the inconsistent usage of golden passage in the training and inference phases. To alleviate these limitations, in this paper, we propose a framework with Multifaceted Improvements for Conversational open-domain Question Answering (MICQA). Specifically, MICQA has three significant advantages. First, the proposed KL-divergence based regularization is able to lead to a better question understanding for retrieval and answer reading. Second, the added post-ranker module can push more relevant passages to the top placements and be selected for reader with a two-aspect constrains. Third, the well designed curriculum learning strategy effectively narrows the gap between the golden passage settings of training and inference, and encourages the reader to find true answer without the golden passage assistance. Extensive experiments conducted on the publicly available dataset OR-QuAC demonstrate the superiority of MICQA over the state-of-the-art model in conversational OpenQA task.

cs.CL↗

arXiv2021

Atomic structure of the continuous random network of amorphous C[(C6H4)2]2, PAF-1

We demonstrate that the amorphous material PAF-1, C[(C6H4)2]2, forms a continuous random network in which tetrahedral carbon sites are connected by 4,4'-biphenyl linkers. Experimental neutron total scattering measurements on deuterated, hydrogenous, and null-scattering samples agree with molecular dynamics simulations based on this model. From the MD model, we are able for the first time to interrogate the atomistic structure. The small-angle scattering is consistent with Porod scattering from particle surfaces, of the form Q^{-4}, where Q is the scattering vector. We measure a distinct peak in the scattering at Q = 0.45 Å^{-1}, corresponding to the first sharp diffraction peak in amorphous silica, which indicates the structural analogy between these two amorphous tetrahedral networks.

cond-mat.dis-nn↗

arXiv2017

Regression analysis of doubly truncated data

Doubly truncated data are found in astronomy, econometrics and survival analysis literature. They arise when each observation is confined to an interval, i.e., only those which fall within their respective intervals are observed along with the intervals. Unlike the more widely studied one-sided truncation that can be handled effectively by the counting process-based approach, doubly truncated data are much more difficult to handle. In their analysis of an astronomical data set, Efron and Petrosian (1999) proposed some nonparametric methods, including a generalization of Kendall's tau test, for doubly truncated data. Motivated by their approach, as well as by the work of Bhattacharya et al. (1983) for right truncated data, we proposed a general method for estimating the regression parameter when the dependent variable is subject to the double truncation. It extends the Mann-Whitney-type rank estimator and can be computed easily by existing software packages. We show that the resulting estimator is consistent and asymptotically normal. A resampling scheme is proposed with large sample justification for approximating the limiting distribution. The quasar data in Efron and Petrosian (1999) are re-analyzed by the new method. Simulation results show that the proposed method works well. Extension to weighted rank estimation are also given.

stat.ME↗